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IUPAC nomenclature Numerical - Organic Chemistry: Some Basic Principals & Techniques, Class 11 Video Lecture

FAQs on IUPAC nomenclature Numerical - Organic Chemistry: Some Basic Principals & Techniques, Class 11 Video Lecture

1. What are the basic principles of IUPAC nomenclature in organic chemistry?
Ans. The basic principles of IUPAC nomenclature in organic chemistry include: - The longest continuous carbon chain in the molecule is selected as the parent chain. - The parent chain is numbered in such a way that the substituents, such as functional groups or branches, have the lowest possible locants. - The names of substituents are written as prefixes and are arranged in alphabetical order. - The type and position of functional groups are indicated by suffixes or prefixes. - If there are multiple identical substituents, prefixes such as di-, tri-, tetra-, etc., are used to indicate their number.
2. What are the techniques used in IUPAC nomenclature in organic chemistry?
Ans. The techniques used in IUPAC nomenclature in organic chemistry are as follows: - Identifying the parent chain: The longest continuous carbon chain in the molecule is identified as the parent chain. - Numbering the parent chain: The parent chain is numbered in such a way that the substituents have the lowest possible locants. - Naming substituents: Substituents, such as functional groups or branches, are named as prefixes and arranged in alphabetical order. - Indicating functional groups: The type and position of functional groups are indicated by suffixes or prefixes. - Using numerical prefixes: If there are multiple identical substituents, numerical prefixes such as di-, tri-, tetra-, etc., are used to indicate their number.
3. How do you select the parent chain in IUPAC nomenclature?
Ans. In IUPAC nomenclature, the parent chain is selected based on the longest continuous carbon chain in the molecule. The parent chain is usually the chain that contains the functional group with the highest priority according to the IUPAC priority rules. The chain may be straight or branched, and it should contain the maximum number of carbon atoms. If there are multiple chains of the same length, the chain with the maximum number of substituents or branches is selected as the parent chain.
4. How do you assign locants in IUPAC nomenclature?
Ans. Locants in IUPAC nomenclature are assigned to indicate the position of substituents or functional groups on the parent chain. The locants are assigned by numbering the parent chain in such a way that the substituents have the lowest possible locants. The numbering starts from the end that gives the lowest locant to the first substituent encountered. If there are multiple substituents, the numbering is continued in the direction that gives the lowest locants to all substituents. If there is a choice between two numbering systems, the one that gives the lowest locants to more substituents is selected.
5. How are functional groups indicated in IUPAC nomenclature?
Ans. Functional groups in IUPAC nomenclature are indicated by suffixes or prefixes. Suffixes are used when the functional group is the principal functional group in the molecule, while prefixes are used when there are other functional groups present. The suffixes are added to the end of the parent chain name and indicate the type of functional group present. For example, "ol" is used for alcohols, "one" is used for ketones, and "oic acid" is used for carboxylic acids. Prefixes, on the other hand, are added before the parent chain name and indicate the type and position of functional groups. For example, "hydroxy" is used for alcohols and "oxy" is used for ethers.
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