Class 12 Exam  >  Class 12 Videos  >  L25 : Lowering of Vapor pressure: Numerical - Solutions, Chemistry, Class 12

L25 : Lowering of Vapor pressure: Numerical - Solutions, Chemistry, Class 12 Video Lecture

FAQs on L25 : Lowering of Vapor pressure: Numerical - Solutions, Chemistry, Class 12 Video Lecture

1. How does lowering of vapor pressure affect the boiling point of a liquid?
Ans. When the vapor pressure of a liquid is lowered, it means that the liquid's molecules are less likely to escape into the gas phase. This results in an increase in the boiling point of the liquid. The higher the vapor pressure, the easier it is for the liquid to vaporize, leading to a lower boiling point.
2. Why does adding a non-volatile solute lower the vapor pressure of a solvent?
Ans. Adding a non-volatile solute to a solvent lowers its vapor pressure due to the phenomenon known as Raoult's law. According to this law, the presence of a solute decreases the number of solvent molecules available to escape into the gas phase, thus reducing the overall vapor pressure. This decrease in vapor pressure leads to a lowering of the boiling point of the solvent.
3. How does the concentration of a solute affect the decrease in vapor pressure of a solvent?
Ans. The decrease in vapor pressure of a solvent due to the addition of a solute is directly proportional to the concentration of the solute. As the concentration of the solute increases, more solvent molecules are replaced by solute particles at the surface, resulting in a greater reduction in the number of solvent molecules available to vaporize. Thus, a higher solute concentration leads to a larger decrease in vapor pressure.
4. What is the relationship between lowering of vapor pressure and colligative properties of solutions?
Ans. The lowering of vapor pressure is one of the colligative properties of solutions. Colligative properties depend on the number of solute particles present in a solution, rather than the nature of the solute itself. When a non-volatile solute is added to a solvent, it lowers the vapor pressure of the solvent according to Raoult's law. This decrease in vapor pressure is a colligative property, meaning it depends on the concentration of solute particles rather than their identity.
5. Can the lowering of vapor pressure be reversed?
Ans. The lowering of vapor pressure due to the addition of a non-volatile solute to a solvent is a reversible process. If the solute is removed from the solution, the vapor pressure of the solvent will return to its original value. Similarly, if the concentration of the solute is reduced, the vapor pressure will increase. The reversibility of the lowering of vapor pressure is one of the key characteristics of colligative properties.
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