Kiara Kapoor

EduRev Mathematics

Kiara Kapoor
EduRev Mathematics
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Discussed Questions
Biswa Nath upvoted   •  Jun 25, 2023

The complex [Fe(phen)2(NCS)2]   (phen = 1,10–phenanthroline) shows spin cross–over behavior.CFSE and µeff at 250 and 150 K, respectively are:
  • a)
    0.4 ∆o, 4.90 BM and 2.4 ∆o, 0.00 BM
  • b)
    2.4 ∆o, 2.90 BM and 0.4 ∆o, 1.77 BM
  • c)
    2.4 ∆o, 0.00 BM and 0.4 ∆o, 4.90 BM
  • d)
    1.2 ∆o, 4.90 BM and 2.4 ∆o, 0.00 BM 
Correct answer is option 'A'. Can you explain this answer?

Yash Roy answered
Spin Crossover Behavior in [Fe(phen)2(NCS)2]

CFSE and eff at 250 and 150 K, respectively are given for the complex [Fe(phen)2(NCS)2]. Let's understand the spin crossover behavior of this complex and how it affects the CFSE and effective magnetic moment (eff) values.

Spin Crossover Behavior

Spin crossover is a phenomenon where a coordination compound undergoes a rev
... more

Biswa Nath upvoted   •  Jun 23, 2023

The infra–red starching frequency vCO of P-S follows the order:



  • a)
    P > R > S > Q
  • b)
    S > P > R > Q
  • c)
    Q > S > P > R
  • d)
    R > Q > P > S
Correct answer is option 'D'. Can you explain this answer?

Suman answered
If we look at the M.O of CO we find HOMO is the non bonding orbital which has some antibonding character also so when CO adduct with BH3 it acts only as sigma bond donner .For this purpose CO give electron from non bonding orbital which has some antibonding character also so bond strangth increases for BH3 adduct ..and adduct with Mn(+) and V(-) it works as sigma donner aswell as pi accepter and a... more

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