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Let S be the sample space of all 3 x 3 matrices with entries from the set {0, 1}. Let the events E1 and E2 be given by
E1 = {A ∈ S : det A = 0} and
E2 ={A ∈ S : sum of entries of A is 7}
If a matrix is chosen at random from S, then the conditional probability P(E1/E2) equals _____
    Correct answer is '0.50'. Can you explain this answer?

    Sahana Ahuja answered
    n(E2) = arrangement of 7, 1 and 2 or
    both zero should be in a row or a column
    (number of ways of arranging of (1, 0, 0) = 3 and arrangement of row = 3
    total = 9 in same way for (1, 0, 0) for columns number of ways will be = 9 total ways = 18

    On dissolving 0.5 g of a non-volatile non-ionic solute to 39 g of benzene, its vapour pressure decreases
    from 650 mm Hg to 640 mm Hg. The depression of freezing point of benzene (in K) upon addition of the
    solute is
    (Given data: Molar mass and the molal freezing point depression constant of benzene are 78 g mol-1 and 5.12 K kg mol–1, respectively)
      Correct answer is '1.02'. Can you explain this answer?

      Ishani Menon answered
      -1
      , respectively)

      We can use the equation for the depression of freezing point:

      ΔTf = Kf · m

      where ΔTf is the change in freezing point, Kf is the molal freezing point depression constant, and m is the molality of the solute.

      First, we need to find the molality of the solute:

      molality = moles of solute / mass of solvent (in kg)

      The mass of benzene is 39 g, which is 0.039 kg. The molar mass of the solute is not given, so we cannot find the moles directly. However, we are given the mass of the solute, which is 0.5 g. We can assume that the solute is non-ionic and non-volatile, which means that it does not affect the vapor pressure of benzene. Therefore, we can use Raoult's law to find the moles of benzene:

      Ptotal = Pbenzene + Psolute

      where Ptotal is the total vapor pressure, Pbenzene is the vapor pressure of pure benzene, and Psolute is the vapor pressure of the solute (which is assumed to be zero). We are given that Pbenzene decreases from 650 mm Hg to 640 mm Hg, so the change in vapor pressure is:

      ΔPbenzene = Pbenzene - Pbenzene,pure = 650 mm Hg - 760 mm Hg = -110 mm Hg

      We can use the following equation to find the moles of benzene:

      nbenzene = (Pbenzene / Patm) · V / RT

      where Patm is the atmospheric pressure (which we assume to be 1 atm), V is the volume of benzene (which we assume to be equal to its mass divided by its density, 0.879 g/mL), R is the gas constant, and T is the temperature (which is not given, but we assume to be room temperature, around 25°C or 298 K).

      Plugging in the values, we get:

      nbenzene = (650 mm Hg / 760 mm Hg) · (0.039 kg / 0.879 g/mL) / (0.0821 L·atm/mol·K · 298 K) ≈ 0.0014 mol

      Since the solute is non-volatile, its mass will not affect the vapor pressure of benzene. Therefore, we can assume that the new mass of benzene is still 39 g. The mass of the solute is 0.5 g, so the total mass of the solution is 39.5 g. The molality of the solute is:

      molality = moles of solute / mass of solvent (in kg) = 0.5 g / 0.039 kg ≈ 12.8 mol/kg

      Now we can use the equation for the depression of freezing point:

      ΔTf = Kf · m

      Plugging in the values, we get:

      ΔTf = 5.12 K kg/mol · 12.8 mol/kg ≈ 65.5 K

      Therefore, the depression of freezing point of benzene upon addition of the solute is approximately 65.5 K.

      At 143 K, the reaction of XeF4 with O2F2 produces xenon compound Y. The total number of lone Pair(s) of electrons present on the whole molecule of Y is ………
        Correct answer is '19.00'. Can you explain this answer?

        Sagar Kapoor answered
        To determine the number of lone pairs of electrons on the molecule of Y, we first need to write the balanced chemical equation for the reaction of XeF4 with O2F2:

        XeF4 + 2O2F2 -> XeOF4 + 2OF2

        From this equation, we can see that the product Y is XeOF4. To determine the number of lone pairs of electrons on XeOF4, we need to draw its Lewis structure.

        First, we determine the total number of valence electrons in XeOF4:

        Xe: 8 valence electrons
        O: 6 valence electrons x 4 = 24 valence electrons
        Total: 32 valence electrons

        We then arrange the atoms in the molecule with Xe as the central atom:

        F
        |
        O Xe O
        |
        F

        Each bond in the molecule represents two electrons, so we can subtract 8 electrons for the four Xe-O bonds:

        32 valence electrons - 8 electrons in Xe-O bonds = 24 electrons

        We then distribute the remaining 24 electrons as lone pairs around the atoms:

        F
        |
        O Xe O
        | || |
        e- LP e-
        |
        F

        Each lone pair represents two electrons, so we can count the number of lone pairs to find the total number of lone pair electrons on the molecule:

        4 lone pairs x 2 electrons per lone pair = 8 electrons

        Therefore, the total number of lone pair electrons on the whole molecule of XeOF4 (product Y) is 8.

        Molar conductivity (∧m) of aqueous solution of sodium stearate, which behaves as a strong electrolyte, isrecorded at varying concentrations (c) of sodium stearate. Which one of the following plots provides thecorrect representation of micelle formation in the solution?
        (critical micelle concentration (CMC) is marked with an arrow in the figures
        • a)
        • b)
        • c)
        • d)
        Correct answer is option 'B'. Can you explain this answer?

        Anjali Sharma answered
        As the concentration of sodium stearate increases beyond 
        , stearate ions get clubbed together and form micelles. This abruptly causes the concentration of the current carrier anions to decreases. This is reflected by the sharp change in 
         at 
        , followed by a greater rate of decrease of 
         with underoot

        Each of the following options contains a set of four molecules, Identify the option(s) where all four molecules possess permanent dipole moment at room temperature.
        • a)
          SO2, C6H5Cl, H2Se, BrF5
        • b)
          BeCl2, CO2, BCl3, CHCl3
        • c)
          BF3, O3, SF6, XeF6
        • d)
          NO2, NH3, POCl3, CH3Cl
        Correct answer is option 'A,D'. Can you explain this answer?

        Suyash Mehra answered

        Explanation:

        Option A: SO2, C6H5Cl, H2Se, BrF5
        - SO2 (Sulfur dioxide), C6H5Cl (Chlorobenzene), H2Se (Hydrogen selenide), and BrF5 (Bromine pentafluoride) all have permanent dipole moments due to the presence of polar bonds in their molecular structures. These molecules are asymmetrical and have a net dipole moment, making them polar.

        Option D: NO2, NH3, POCl3, CH3Cl
        - NO2 (Nitrogen dioxide), NH3 (Ammonia), POCl3 (Phosphoryl chloride), and CH3Cl (Chloromethane) also exhibit permanent dipole moments at room temperature. These molecules have polar bonds and are asymmetrical, resulting in a non-zero net dipole moment.

        Therefore, options A and D contain sets of molecules that possess permanent dipole moments at room temperature.

        Let L1 and L2 denote the lines and respectively. If L3 is a line which is perpendicular to both L1 and L2 and cuts both of them, then which of the following options describe (s) L3?
        • a)
        • b)
        • c)
        • d)
        Correct answer is option 'A,B,C'. Can you explain this answer?

        Disha Tiwari answered


        L1 & L2 are skew lines The direction ratios of line AB which is perpendicular to L1 and L2 will be

        Hence direction ratios of AB will be (2, 2, –1) direction ratios of AB proportional to (2, 2, –1)

        solving (i) (ii) & (iii) we get λ = 1/9

        Equation of line L3 (A, B) passing through A

        option (A) correct Equation of line L3 passing through B

        Option (C) is correct, option (B) also satisfy

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