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All questions of JEE Advanced 2015 for JEE Exam

In the following circuit, the current through the resistor R (=2) is I Amperes. The value of I is
    Correct answer is '1'. Can you explain this answer?

    Vikas Saini answered
    1ohm/2ohm and 2ohm/4ohm are balanced wheat stone bridge,so 8ohm R will be removed then after solvinge them 2ohm R will come.Then 6ohm/12ohm And 2ohm/4ohm are in balanced wheat stone bridge then 10ohm resistance will be removed.Reff comes 6.5 ohm.I=V/R=6.5/6.5=1ANS

    The correct statement(s) regarding, (i) HClO, (ii) HClO2, (iii) HClO3 and (iv) HClO4, is (are)
    • a)
      The number of Cl = O bonds in (ii) and (iii) together is two
    • b)
      The number of lone pairs of electrons on Cl in (ii) and (iii) together is three
    • c)
      The hybridization of Cl in (iv) is sp3
    • d)
      Amongst (i) to (iv), the strongest acid is (i)
    Correct answer is option 'B,C'. Can you explain this answer?

    Nisha Kaur answered
    Statement (i): HClO
    HClO is hypochlorous acid. It contains one chlorine atom, one hydrogen atom, and one oxygen atom. The chlorine atom is bonded to the oxygen through a single bond and the oxygen atom has two lone pairs of electrons. Therefore, the correct statement about HClO is that it has one Cl = O bond and two lone pairs of electrons on chlorine.

    Statement (ii): HClO2
    HClO2 is chlorous acid. It contains one chlorine atom, one hydrogen atom, and two oxygen atoms. The chlorine atom is bonded to one of the oxygen atoms through a single bond and to the other oxygen atom through a double bond. The oxygen atoms have a total of three lone pairs of electrons. Therefore, the correct statement about HClO2 is that it has one Cl = O bond and three lone pairs of electrons on chlorine.

    Statement (iii): HClO3
    HClO3 is chloric acid. It contains one chlorine atom, one hydrogen atom, and three oxygen atoms. The chlorine atom is bonded to each of the oxygen atoms through a single bond. The oxygen atoms have a total of four lone pairs of electrons. Therefore, the correct statement about HClO3 is that it has three Cl = O bonds and four lone pairs of electrons on chlorine.

    Statement (iv): HClO4
    HClO4 is perchloric acid. It contains one chlorine atom, one hydrogen atom, and four oxygen atoms. The chlorine atom is bonded to each of the oxygen atoms through a single bond. The oxygen atoms have a total of five lone pairs of electrons. Therefore, the correct statement about HClO4 is that it has four Cl = O bonds and five lone pairs of electrons on chlorine.

    Correct Statements:
    Based on the above analysis, the correct statements are:

    a) The number of Cl = O bonds in (ii) and (iii) together is two.
    In HClO2, there is one Cl = O bond.
    In HClO3, there are three Cl = O bonds.
    Therefore, the total number of Cl = O bonds in (ii) and (iii) together is two.

    b) The number of lone pairs of electrons on Cl in (ii) and (iii) together is three.
    In HClO2, there are three lone pairs of electrons on the chlorine atom.
    In HClO3, there are four lone pairs of electrons on the chlorine atom.
    Therefore, the total number of lone pairs of electrons on Cl in (ii) and (iii) together is three.

    c) The hybridization of Cl in (iv) is sp3
    In HClO4, there are four Cl = O bonds and five lone pairs of electrons on the chlorine atom. This indicates that the chlorine atom is sp3 hybridized.

    Therefore, the correct statements are (b) and (c).

    When O2  is adsorbed on a metallic surface, electron transfer occurs from the metal to O2. The TRUE
    statement(s) regarding this adsorption is(are)
    • a)
      O2 is physisorbed
    • b)
      heat is released
    • c)
      occupancy of π*2p of O2 is increased
    • d)
      bond length of O2 is increased
    Correct answer is option 'B,C,D'. Can you explain this answer?

    Disha Khanna answered
    * Adsorption of O2 on metal surface is exothermic.
    * During electron transfer from metal to O2 electron occupies π*2p orbital of O2.
    * Due to electron transfer to O2 the bond order of O2 decreases hence bond length increases

    Three moles of B2H6 are completely reacted with methanol. The number of moles of boron containing
    product formed is
      Correct answer is '6'. Can you explain this answer?

      1 mole of B2H6 reacts with 6 mole of MeOH to give 2 moles of B(OMe)3.
      3 mole of B2H6 will react with 18 mole of MeOH to give 6 moles of B(OMe)3

      Let n be the number of ways in which 5 boys and 5 girls can stand in a queue in such a way that all the girls
      stand consecutively in the queue. Let m be the number of ways in which 5 boys and 5 girls can stand in a
      queue in such a way that exactly four girls stand consecutively in the queue. Then the value of m/n is 
        Correct answer is '5'. Can you explain this answer?

        Anshu Gupta answered
        Solution:

        Finding n:
        To find the total number of ways in which 5 boys and 5 girls can stand in a queue such that all the girls stand consecutively, we can group the 5 girls together and treat them as a single entity. So, we have 6 entities to be arranged in a queue, which can be done in 6! ways. Also, the 5 girls can be arranged among themselves in 5! ways. Therefore, the total number of ways in which 5 boys and 5 girls can stand in a queue such that all the girls stand consecutively is:

        n = 6! × 5! = 720 × 120 = 86400

        Finding m:
        To find the number of ways in which exactly four girls stand consecutively, we can select any four girls out of the five in 5 ways. Then, we can group these four girls together and treat them as a single entity. So, we have 6 entities to be arranged in a queue, which can be done in 6! ways. Also, the four girls can be arranged among themselves in 4! ways, and the remaining girl can be placed in any of the 5 gaps between the groups of four girls or to the left or right of the group. Therefore, the total number of ways in which 5 boys and 5 girls can stand in a queue such that exactly four girls stand consecutively is:

        m = 5 × 6! × 4! × 5 = 6000

        Finding m/n:
        The required value is m/n:

        m/n = 6000/86400 = 5/72

        Therefore, the correct option is 5.

        The % yield of ammonia as a function of time in the reaction
        If this reaction is conducted at (P, T2), with T2 > T1, the % yield of ammonia as a function of time is
        represented by
        • a)
        • b)
        • c)
        • d)
        Correct answer is option 'B'. Can you explain this answer?

        Krishna Iyer answered
        Increasing the temperature lowers equilibrium yield of ammonia.
        However, at higher temperature the initial rate of forward reaction would be greater than at lower
        temperature that is why the percentage yield of NH3 too would be more initially.

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