Given:
Initial gauge pressure, P₁ = 1 bar
Initial temperature, T₁ = 15°C = 288 K
Final temperature, T₂ = 5°C = 278 K
Volume of football, V = 2500 cm³ = 2.5 × 10⁻³ m³
Volume constant
Gauge pressure means: P_gauge = P_absolute − P_atm
Atmospheric pressure P_atm = 1 bar = 10⁵ Pa
Air inside is treated as ideal gas
R = 8.314 J/mol·K
Molar mass of air M = 29 g/mol
Step 1: Find absolute initial pressure P₁ absolute
P₁(absolute) = P_atm + P_gauge = 1 + 1 = 2 bar = 2 × 10⁵ Pa
Step 2: Use ideal gas law to find number of moles n:
P V = n R T ⇒ n = (P V) / (R T)
n = (2 × 10⁵ × 2.5 × 10⁻³) / (8.314 × 288) = 500 / 2395.6 ≈ 0.2088 mol
Step 3: Find final pressure P₂ (absolute):
Since volume and amount of gas n are constant,
P₁ / T₁ = P₂ / T₂ ⇒ P₂ = P₁ × (T₂ / T₁) = 2 × 10⁵ × (278 / 288) = 1.93 × 10⁵ Pa
Step 4: Calculate final gauge pressure:
P_gauge,2 = P₂ − P_atm = 1.93 × 10⁵ − 1 × 10⁵ = 0.93 × 10⁵ Pa = 0.93 bar
Step 5: Calculate heat lost by the air (assuming air as ideal diatomic gas, C_V = (5/2) R):
Change in internal energy:
Q = n C_V ΔT = n × (5/2) × R × (T₂ − T₁)
Q = 0.2088 × 2.5 × 8.314 × (278 − 288)
Q = 0.2088 × 20.785 × (−10)
Q = 0.2088 × (−207.85) = −43.4 J
The negative sign indicates heat is lost.
Final answers:
Heat lost ≈ 43.7 J
Gauge pressure at stadium ≈ 0.93 bar
Correct option is:
c) 43.7 J, 0.93 bar