Page 1
Cement
Chemical Composition
Ordinary cement contains two basic ingredients, namely,
argillaceous and calcareous. In argillaceous materials,
clay predominates and in calcareous calcium carbonate
predominates.
Broadly, the raw materials used for manufacture of
cement consist mainly of lime, silica, alumina and iron
oxide. These oxides interact with one another at high tem-
perature and form more complex compounds. The relative
proportions of these oxide compounds are responsible for
influencing the various properties of cement, in addition to
rate of cooling and fineness of grinding.
Approximate oxide composition ranges for ordinary
portland cement (OPC) are:
Ingredient Chemical Formula Range (%)
Lime CaO 62–67
Silica SiO
2
17–25
Alumina Al
2
O
3
3–8
Calcium Sulphate CaSO
4
3–4
Iron oxide Fe
2
O
3
3–4
Magnesia MgO 1–3
Sulphur S 1–3
Alkalies – 0.2–1
Functions of Cement Ingredients
1. Lime (CaO): Excess lime makes the cement unsound
and causes the cement to expand and disintegrate.
Deficiency in lime makes loss of strength and makes
cement to set quickly.
2. Silica (SiO
2
): SiO
2
imparts the strength to cement
by forming the di-calcium and tri-calcium silicates.
Excess silica makes the strength of cement increases,
but prolongs the setting time.
3. Alumina (Al
2
O
3
): Al
2
O
3
imparts quick setting
property to the cement. It acts as a flux and lowers
the clinkering temperature. Excess alumina makes
cement weaker.
4. Calcium Sulphate (CaSO
4
): It is in the form of
gypsum and increases the initial setting time of
cement.
5. Iron Oxide (Fe
2
O
3
): Fe
2
O
3
imparts colour, hardness
and strength to cement.
6. Magnesia (MgO): MgO imparts hardness and
colour, if present in small amount. Excess MgO
makes cement unsound.
7. Sulphur (S): It is useful in making sound cement.
8. Alkalis: Most of the alkalis present in raw materials are
carried away by the flue gases during heating process.
Presence of alkalis causes problems such as alkali-
aggregate reaction, efflorescence and staining, etc.
Concrete and Its Constituents
Part III_Unit 4_Chapter 01.indd 253 5/20/2017 7:25:32 PM
Page 2
Cement
Chemical Composition
Ordinary cement contains two basic ingredients, namely,
argillaceous and calcareous. In argillaceous materials,
clay predominates and in calcareous calcium carbonate
predominates.
Broadly, the raw materials used for manufacture of
cement consist mainly of lime, silica, alumina and iron
oxide. These oxides interact with one another at high tem-
perature and form more complex compounds. The relative
proportions of these oxide compounds are responsible for
influencing the various properties of cement, in addition to
rate of cooling and fineness of grinding.
Approximate oxide composition ranges for ordinary
portland cement (OPC) are:
Ingredient Chemical Formula Range (%)
Lime CaO 62–67
Silica SiO
2
17–25
Alumina Al
2
O
3
3–8
Calcium Sulphate CaSO
4
3–4
Iron oxide Fe
2
O
3
3–4
Magnesia MgO 1–3
Sulphur S 1–3
Alkalies – 0.2–1
Functions of Cement Ingredients
1. Lime (CaO): Excess lime makes the cement unsound
and causes the cement to expand and disintegrate.
Deficiency in lime makes loss of strength and makes
cement to set quickly.
2. Silica (SiO
2
): SiO
2
imparts the strength to cement
by forming the di-calcium and tri-calcium silicates.
Excess silica makes the strength of cement increases,
but prolongs the setting time.
3. Alumina (Al
2
O
3
): Al
2
O
3
imparts quick setting
property to the cement. It acts as a flux and lowers
the clinkering temperature. Excess alumina makes
cement weaker.
4. Calcium Sulphate (CaSO
4
): It is in the form of
gypsum and increases the initial setting time of
cement.
5. Iron Oxide (Fe
2
O
3
): Fe
2
O
3
imparts colour, hardness
and strength to cement.
6. Magnesia (MgO): MgO imparts hardness and
colour, if present in small amount. Excess MgO
makes cement unsound.
7. Sulphur (S): It is useful in making sound cement.
8. Alkalis: Most of the alkalis present in raw materials are
carried away by the flue gases during heating process.
Presence of alkalis causes problems such as alkali-
aggregate reaction, efflorescence and staining, etc.
Concrete and Its Constituents
Part III_Unit 4_Chapter 01.indd 253 5/20/2017 7:25:32 PM
The above mentioned constituents in chemical reactions
form the following compounds, called ‘bogue’ s compounds’.
Tri-calcium silicate (Alite) C
3
S 45%
Di-calcium silicate (Belite) C
2
S 25%
Tri-calcium Aluminate (celite) C
3
A 11%
Tetra-calcium Alumino Ferrite (Felite) C
4
AF 9%
The functions of each of these compounds are as follows:
1. C
3
S
• Hydrates quickly and contributes more to the early
strength.
• High heat of hydration.
2. C
2
S
• Strengthen the concrete from 7days – 1 year.
• Less heat of hydration.
• Initial setting of cement.
3. C
3
A
• Small contribution to the strength within first 24 hours.
• Very high heat of hydration.
4. C
4
AF
• Comparatively inactive.
Types of Cements
1. Ordinary portland cement (OPC):
• OPC is used in general concrete construction
where there is no exposure to sulphates in soil or
in groundwater.
• Initial and final setting times are 30 minutes and
10 hours.
Different Grades of Ordinary Portland Cement (OPC)
Grade of
Cement
Details
33 grade
ordinary
portland
cement
(IS:269-
1998)
• The compressive strength after 28 days
is 33 N/mm
2
.
• Used for general construction works in
normal environmental conditions.
• Cannot be used where higher grade
concrete above M20 is required.
43 grade
ordinary
portland
cement
(IS:8112-
2000)
• Minimum 28 days compressive strength
43 N/mm
2
.
• Used for construction of residential,
commercial and industrial building, roads,
bridges, flyovers, irrigation projects and
other general civil construction works.
• Suitable for all types of applications
RCC, plastering, masonry, etc.
53 grade
ordinary
portland
cement
(IS:12269-
1999)
• Minimum 28 days compressive strength
53 N/mm
2
.
• Gives 10–15% saving in cement
consumption and 5–8% saving in steel
consumption provided higher grades of
concrete, say M30 and above.
• Useful for high-rise buildings, bridges, flyo-
ver, chimneys and pre-stressed structures
where high-grade concrete is required.
• Gives better durability characteristics to
concrete.
2. Rapid hardening cement:
• Contains high percentage of C
3
S to the extent
about 56%.
• 3 days strength is equivalent to 7 days strength of
OPC.
• Initial and final setting times are as same as OPC.
Advantages:
• Sets rapidly and requires a short period of curing.
• Early removal of formwork.
3. Extra rapid hardening cement:
• Imparts strength about 25% higher than that of
rapid hardening cement.
• It is obtained by inter-grinding calcium chloride
(CaCl
2
) with rapid hardening of portland cement.
4. Low heat cement:
• Contains lower % of C
3
A of about 5% and higher %
of C
2
S about 46%.
• Initial setting time is about an hour and final setting
time is about 10 hours.
• Mainly used for mass concrete works.
5. Hydrophobic cement:
• Contains admixtures which decrease the wetting
ability of cement grains.
• Frost resistance and water resistance of concrete
can be increased by using this type of cement.
• Examples for hydrophobic admixtures includes oleic
acid, oxidized petroleum, naphthalene, soap, etc.
6. Quick setting cement:
• Produced by adding small percentage of alumin-
ium sulphate and by finely grinding the cement.
• Setting action starts within 5 minutes after addition
of water and within 30 minutes it hardens.
• Used to lay concrete under water.
7. Expanding cement:
• Produced by adding an expanding medium like
sulpho-aluminate and a stabilizing agent to OPC.
• Used for repairing damaged concrete surfaces and
for construction of water retaining structures.
8. High alumina cement:
• Produced by grinding clinkers formed by calcined
bauxite and lime.
• Initial setting time is more than 3
1
2
hours and final
setting time is about 5 hours.
• Acid resistant, but high heat of hydration.
9. Pozzolana cement:
• Pozzolana is a silicacious material which has no
cementitious properties when it is used alone, but
in the presence of cement it posses cementitious
properties.
• Pozzolana materials should be between 10–30%.
• Fly ash, blast furanace slag, silica fume are exam-
ples for artificial pozzolans and burnt clay, pumic-
ite are examples for natural pozzolana materials.
Part III_Unit 4_Chapter 01.indd 254 5/20/2017 7:25:32 PM
Page 3
Cement
Chemical Composition
Ordinary cement contains two basic ingredients, namely,
argillaceous and calcareous. In argillaceous materials,
clay predominates and in calcareous calcium carbonate
predominates.
Broadly, the raw materials used for manufacture of
cement consist mainly of lime, silica, alumina and iron
oxide. These oxides interact with one another at high tem-
perature and form more complex compounds. The relative
proportions of these oxide compounds are responsible for
influencing the various properties of cement, in addition to
rate of cooling and fineness of grinding.
Approximate oxide composition ranges for ordinary
portland cement (OPC) are:
Ingredient Chemical Formula Range (%)
Lime CaO 62–67
Silica SiO
2
17–25
Alumina Al
2
O
3
3–8
Calcium Sulphate CaSO
4
3–4
Iron oxide Fe
2
O
3
3–4
Magnesia MgO 1–3
Sulphur S 1–3
Alkalies – 0.2–1
Functions of Cement Ingredients
1. Lime (CaO): Excess lime makes the cement unsound
and causes the cement to expand and disintegrate.
Deficiency in lime makes loss of strength and makes
cement to set quickly.
2. Silica (SiO
2
): SiO
2
imparts the strength to cement
by forming the di-calcium and tri-calcium silicates.
Excess silica makes the strength of cement increases,
but prolongs the setting time.
3. Alumina (Al
2
O
3
): Al
2
O
3
imparts quick setting
property to the cement. It acts as a flux and lowers
the clinkering temperature. Excess alumina makes
cement weaker.
4. Calcium Sulphate (CaSO
4
): It is in the form of
gypsum and increases the initial setting time of
cement.
5. Iron Oxide (Fe
2
O
3
): Fe
2
O
3
imparts colour, hardness
and strength to cement.
6. Magnesia (MgO): MgO imparts hardness and
colour, if present in small amount. Excess MgO
makes cement unsound.
7. Sulphur (S): It is useful in making sound cement.
8. Alkalis: Most of the alkalis present in raw materials are
carried away by the flue gases during heating process.
Presence of alkalis causes problems such as alkali-
aggregate reaction, efflorescence and staining, etc.
Concrete and Its Constituents
Part III_Unit 4_Chapter 01.indd 253 5/20/2017 7:25:32 PM
The above mentioned constituents in chemical reactions
form the following compounds, called ‘bogue’ s compounds’.
Tri-calcium silicate (Alite) C
3
S 45%
Di-calcium silicate (Belite) C
2
S 25%
Tri-calcium Aluminate (celite) C
3
A 11%
Tetra-calcium Alumino Ferrite (Felite) C
4
AF 9%
The functions of each of these compounds are as follows:
1. C
3
S
• Hydrates quickly and contributes more to the early
strength.
• High heat of hydration.
2. C
2
S
• Strengthen the concrete from 7days – 1 year.
• Less heat of hydration.
• Initial setting of cement.
3. C
3
A
• Small contribution to the strength within first 24 hours.
• Very high heat of hydration.
4. C
4
AF
• Comparatively inactive.
Types of Cements
1. Ordinary portland cement (OPC):
• OPC is used in general concrete construction
where there is no exposure to sulphates in soil or
in groundwater.
• Initial and final setting times are 30 minutes and
10 hours.
Different Grades of Ordinary Portland Cement (OPC)
Grade of
Cement
Details
33 grade
ordinary
portland
cement
(IS:269-
1998)
• The compressive strength after 28 days
is 33 N/mm
2
.
• Used for general construction works in
normal environmental conditions.
• Cannot be used where higher grade
concrete above M20 is required.
43 grade
ordinary
portland
cement
(IS:8112-
2000)
• Minimum 28 days compressive strength
43 N/mm
2
.
• Used for construction of residential,
commercial and industrial building, roads,
bridges, flyovers, irrigation projects and
other general civil construction works.
• Suitable for all types of applications
RCC, plastering, masonry, etc.
53 grade
ordinary
portland
cement
(IS:12269-
1999)
• Minimum 28 days compressive strength
53 N/mm
2
.
• Gives 10–15% saving in cement
consumption and 5–8% saving in steel
consumption provided higher grades of
concrete, say M30 and above.
• Useful for high-rise buildings, bridges, flyo-
ver, chimneys and pre-stressed structures
where high-grade concrete is required.
• Gives better durability characteristics to
concrete.
2. Rapid hardening cement:
• Contains high percentage of C
3
S to the extent
about 56%.
• 3 days strength is equivalent to 7 days strength of
OPC.
• Initial and final setting times are as same as OPC.
Advantages:
• Sets rapidly and requires a short period of curing.
• Early removal of formwork.
3. Extra rapid hardening cement:
• Imparts strength about 25% higher than that of
rapid hardening cement.
• It is obtained by inter-grinding calcium chloride
(CaCl
2
) with rapid hardening of portland cement.
4. Low heat cement:
• Contains lower % of C
3
A of about 5% and higher %
of C
2
S about 46%.
• Initial setting time is about an hour and final setting
time is about 10 hours.
• Mainly used for mass concrete works.
5. Hydrophobic cement:
• Contains admixtures which decrease the wetting
ability of cement grains.
• Frost resistance and water resistance of concrete
can be increased by using this type of cement.
• Examples for hydrophobic admixtures includes oleic
acid, oxidized petroleum, naphthalene, soap, etc.
6. Quick setting cement:
• Produced by adding small percentage of alumin-
ium sulphate and by finely grinding the cement.
• Setting action starts within 5 minutes after addition
of water and within 30 minutes it hardens.
• Used to lay concrete under water.
7. Expanding cement:
• Produced by adding an expanding medium like
sulpho-aluminate and a stabilizing agent to OPC.
• Used for repairing damaged concrete surfaces and
for construction of water retaining structures.
8. High alumina cement:
• Produced by grinding clinkers formed by calcined
bauxite and lime.
• Initial setting time is more than 3
1
2
hours and final
setting time is about 5 hours.
• Acid resistant, but high heat of hydration.
9. Pozzolana cement:
• Pozzolana is a silicacious material which has no
cementitious properties when it is used alone, but
in the presence of cement it posses cementitious
properties.
• Pozzolana materials should be between 10–30%.
• Fly ash, blast furanace slag, silica fume are exam-
ples for artificial pozzolans and burnt clay, pumic-
ite are examples for natural pozzolana materials.
Part III_Unit 4_Chapter 01.indd 254 5/20/2017 7:25:32 PM
• Used to prepare mass concrete of lean mix and for
marine works sewage works and for laying con-
crete under water.
10. White cement and coloured cement:
• Used for finishing, plastering and architectural,
and ornamental works.
• Colouring agents, such as iron oxide, cobalt, man-
ganese dioxide, etc., are added to white cement
to obtain red and yellow, blue and black colour
cements.
Tests on Cement
Field Tests
Carried out to roughly ascertain the quality of cement.
1. Colour:
• Should be uniform and in grey colour with light
greenish shade.
• Gives an indication of excess lime or clay and the
degree of burning.
2. Physical properties:
• Should feel smooth when rubbed between fingers.
• It should sink, but not float when small quantity of
cement thrown in a bucket.
• Should feel cool and not warm when hand is
inserted in a bag/heap of cement.
3. Presence of lumps:
• Should be free from any hard lumps.
Laboratory Tests
1. Fineness:
• Carried out to check proper grinding of cement.
• Determined either by sieve test or by permeability
apparatus test.
• In permeability test, ‘specific surface area’ is cal-
culated as a measure of frequency of the average
size of particles, expressed in cm
2
/g.
• It should not be less than 2250 cm
2
/g for OPC,
3250 cm
2
/gm for rapid hardening and 3200 cm
2
/
gm for low heat cements.
2. Consistency:
• To determine the % of water required for making
workable cement paste.
• Apparatus used: Vicat’ s apparatus with Vicat plunger
of 1 cm diameter.
• As per Vicat’s test, percentage of water added
to cement at which the needle penetration is in
between 5–7 mm (from the bottom of the mould)
is called ‘consistency’.
• For OPC, consistency is around 30%.
3. Setting times:
Initial setting time: Determined by Vicat’ s apparatus
using Vicat’ s needle of 1 mm squared needle.
• Water added to cement is about 0.85 times the
water required for standard consistency. Weight of
the cement taken is 300 g to carry out this test.
• Period elapsing between the time when water is
added to the cement and the time at which the nee-
dle fails to pierce the test block by 5 ± 0.5 mm is
taken as the initial setting time.
• For OPC, it should not be less than 30 minutes.
For low heat cements, it should not be less than 60
minutes.
Final setting time: Determined by Vicat’s apparatus
using Vicat’s needle with annual collar of 5 mm
diameter.
• Time lapsed since addition of water to time at
which needle with annual collar can only make a
mark on hard concrete surface, but not piercing is
taken as final setting time.
• It should not be more than 10 hours for OPC.
4. Soundness:
• Soundness refer to the ability of cement to main-
tain constant volume.
• Carried out to detect the presence of un-combined
lime in cement.
• Determined by Le Chatelier apparatus, or Autoclave
test.
• Le Chatelier’s method measures expansion due to
lime, and Autoclave method measures expansion
due to magnesia.
• Expansion more than 10 mm indicates unsound-
ness of cement.
5. Heat of hydration:
• Hydration is the process of adding water to cement.
• Determined by adiabatic calorimeter test or vac-
uum flask test.
• For OPC, heat of hydration at 7 days should not
be more than 65 cal/g, and at 28 days should not
more than 75 cal/g.
6. Specific gravity:
• Determined through test conducted—using kero-
sene and specific gravity bottle at 27° temperature.
• Specific gravity for OPC is about 3.1.
Some Important Specifications—OPC
Fineness (cm
2
/gm) 2250 minimum
Setting times
Initial 30 hours duration
Final 10 hours maximum
Specific gravity 3.1
Compressive strength (kg/cm
2
)
3 days 230 minimum
7 days 330 minimum
28 days 430 minimum
Part III_Unit 4_Chapter 01.indd 255 5/20/2017 7:25:32 PM
Page 4
Cement
Chemical Composition
Ordinary cement contains two basic ingredients, namely,
argillaceous and calcareous. In argillaceous materials,
clay predominates and in calcareous calcium carbonate
predominates.
Broadly, the raw materials used for manufacture of
cement consist mainly of lime, silica, alumina and iron
oxide. These oxides interact with one another at high tem-
perature and form more complex compounds. The relative
proportions of these oxide compounds are responsible for
influencing the various properties of cement, in addition to
rate of cooling and fineness of grinding.
Approximate oxide composition ranges for ordinary
portland cement (OPC) are:
Ingredient Chemical Formula Range (%)
Lime CaO 62–67
Silica SiO
2
17–25
Alumina Al
2
O
3
3–8
Calcium Sulphate CaSO
4
3–4
Iron oxide Fe
2
O
3
3–4
Magnesia MgO 1–3
Sulphur S 1–3
Alkalies – 0.2–1
Functions of Cement Ingredients
1. Lime (CaO): Excess lime makes the cement unsound
and causes the cement to expand and disintegrate.
Deficiency in lime makes loss of strength and makes
cement to set quickly.
2. Silica (SiO
2
): SiO
2
imparts the strength to cement
by forming the di-calcium and tri-calcium silicates.
Excess silica makes the strength of cement increases,
but prolongs the setting time.
3. Alumina (Al
2
O
3
): Al
2
O
3
imparts quick setting
property to the cement. It acts as a flux and lowers
the clinkering temperature. Excess alumina makes
cement weaker.
4. Calcium Sulphate (CaSO
4
): It is in the form of
gypsum and increases the initial setting time of
cement.
5. Iron Oxide (Fe
2
O
3
): Fe
2
O
3
imparts colour, hardness
and strength to cement.
6. Magnesia (MgO): MgO imparts hardness and
colour, if present in small amount. Excess MgO
makes cement unsound.
7. Sulphur (S): It is useful in making sound cement.
8. Alkalis: Most of the alkalis present in raw materials are
carried away by the flue gases during heating process.
Presence of alkalis causes problems such as alkali-
aggregate reaction, efflorescence and staining, etc.
Concrete and Its Constituents
Part III_Unit 4_Chapter 01.indd 253 5/20/2017 7:25:32 PM
The above mentioned constituents in chemical reactions
form the following compounds, called ‘bogue’ s compounds’.
Tri-calcium silicate (Alite) C
3
S 45%
Di-calcium silicate (Belite) C
2
S 25%
Tri-calcium Aluminate (celite) C
3
A 11%
Tetra-calcium Alumino Ferrite (Felite) C
4
AF 9%
The functions of each of these compounds are as follows:
1. C
3
S
• Hydrates quickly and contributes more to the early
strength.
• High heat of hydration.
2. C
2
S
• Strengthen the concrete from 7days – 1 year.
• Less heat of hydration.
• Initial setting of cement.
3. C
3
A
• Small contribution to the strength within first 24 hours.
• Very high heat of hydration.
4. C
4
AF
• Comparatively inactive.
Types of Cements
1. Ordinary portland cement (OPC):
• OPC is used in general concrete construction
where there is no exposure to sulphates in soil or
in groundwater.
• Initial and final setting times are 30 minutes and
10 hours.
Different Grades of Ordinary Portland Cement (OPC)
Grade of
Cement
Details
33 grade
ordinary
portland
cement
(IS:269-
1998)
• The compressive strength after 28 days
is 33 N/mm
2
.
• Used for general construction works in
normal environmental conditions.
• Cannot be used where higher grade
concrete above M20 is required.
43 grade
ordinary
portland
cement
(IS:8112-
2000)
• Minimum 28 days compressive strength
43 N/mm
2
.
• Used for construction of residential,
commercial and industrial building, roads,
bridges, flyovers, irrigation projects and
other general civil construction works.
• Suitable for all types of applications
RCC, plastering, masonry, etc.
53 grade
ordinary
portland
cement
(IS:12269-
1999)
• Minimum 28 days compressive strength
53 N/mm
2
.
• Gives 10–15% saving in cement
consumption and 5–8% saving in steel
consumption provided higher grades of
concrete, say M30 and above.
• Useful for high-rise buildings, bridges, flyo-
ver, chimneys and pre-stressed structures
where high-grade concrete is required.
• Gives better durability characteristics to
concrete.
2. Rapid hardening cement:
• Contains high percentage of C
3
S to the extent
about 56%.
• 3 days strength is equivalent to 7 days strength of
OPC.
• Initial and final setting times are as same as OPC.
Advantages:
• Sets rapidly and requires a short period of curing.
• Early removal of formwork.
3. Extra rapid hardening cement:
• Imparts strength about 25% higher than that of
rapid hardening cement.
• It is obtained by inter-grinding calcium chloride
(CaCl
2
) with rapid hardening of portland cement.
4. Low heat cement:
• Contains lower % of C
3
A of about 5% and higher %
of C
2
S about 46%.
• Initial setting time is about an hour and final setting
time is about 10 hours.
• Mainly used for mass concrete works.
5. Hydrophobic cement:
• Contains admixtures which decrease the wetting
ability of cement grains.
• Frost resistance and water resistance of concrete
can be increased by using this type of cement.
• Examples for hydrophobic admixtures includes oleic
acid, oxidized petroleum, naphthalene, soap, etc.
6. Quick setting cement:
• Produced by adding small percentage of alumin-
ium sulphate and by finely grinding the cement.
• Setting action starts within 5 minutes after addition
of water and within 30 minutes it hardens.
• Used to lay concrete under water.
7. Expanding cement:
• Produced by adding an expanding medium like
sulpho-aluminate and a stabilizing agent to OPC.
• Used for repairing damaged concrete surfaces and
for construction of water retaining structures.
8. High alumina cement:
• Produced by grinding clinkers formed by calcined
bauxite and lime.
• Initial setting time is more than 3
1
2
hours and final
setting time is about 5 hours.
• Acid resistant, but high heat of hydration.
9. Pozzolana cement:
• Pozzolana is a silicacious material which has no
cementitious properties when it is used alone, but
in the presence of cement it posses cementitious
properties.
• Pozzolana materials should be between 10–30%.
• Fly ash, blast furanace slag, silica fume are exam-
ples for artificial pozzolans and burnt clay, pumic-
ite are examples for natural pozzolana materials.
Part III_Unit 4_Chapter 01.indd 254 5/20/2017 7:25:32 PM
• Used to prepare mass concrete of lean mix and for
marine works sewage works and for laying con-
crete under water.
10. White cement and coloured cement:
• Used for finishing, plastering and architectural,
and ornamental works.
• Colouring agents, such as iron oxide, cobalt, man-
ganese dioxide, etc., are added to white cement
to obtain red and yellow, blue and black colour
cements.
Tests on Cement
Field Tests
Carried out to roughly ascertain the quality of cement.
1. Colour:
• Should be uniform and in grey colour with light
greenish shade.
• Gives an indication of excess lime or clay and the
degree of burning.
2. Physical properties:
• Should feel smooth when rubbed between fingers.
• It should sink, but not float when small quantity of
cement thrown in a bucket.
• Should feel cool and not warm when hand is
inserted in a bag/heap of cement.
3. Presence of lumps:
• Should be free from any hard lumps.
Laboratory Tests
1. Fineness:
• Carried out to check proper grinding of cement.
• Determined either by sieve test or by permeability
apparatus test.
• In permeability test, ‘specific surface area’ is cal-
culated as a measure of frequency of the average
size of particles, expressed in cm
2
/g.
• It should not be less than 2250 cm
2
/g for OPC,
3250 cm
2
/gm for rapid hardening and 3200 cm
2
/
gm for low heat cements.
2. Consistency:
• To determine the % of water required for making
workable cement paste.
• Apparatus used: Vicat’ s apparatus with Vicat plunger
of 1 cm diameter.
• As per Vicat’s test, percentage of water added
to cement at which the needle penetration is in
between 5–7 mm (from the bottom of the mould)
is called ‘consistency’.
• For OPC, consistency is around 30%.
3. Setting times:
Initial setting time: Determined by Vicat’ s apparatus
using Vicat’ s needle of 1 mm squared needle.
• Water added to cement is about 0.85 times the
water required for standard consistency. Weight of
the cement taken is 300 g to carry out this test.
• Period elapsing between the time when water is
added to the cement and the time at which the nee-
dle fails to pierce the test block by 5 ± 0.5 mm is
taken as the initial setting time.
• For OPC, it should not be less than 30 minutes.
For low heat cements, it should not be less than 60
minutes.
Final setting time: Determined by Vicat’s apparatus
using Vicat’s needle with annual collar of 5 mm
diameter.
• Time lapsed since addition of water to time at
which needle with annual collar can only make a
mark on hard concrete surface, but not piercing is
taken as final setting time.
• It should not be more than 10 hours for OPC.
4. Soundness:
• Soundness refer to the ability of cement to main-
tain constant volume.
• Carried out to detect the presence of un-combined
lime in cement.
• Determined by Le Chatelier apparatus, or Autoclave
test.
• Le Chatelier’s method measures expansion due to
lime, and Autoclave method measures expansion
due to magnesia.
• Expansion more than 10 mm indicates unsound-
ness of cement.
5. Heat of hydration:
• Hydration is the process of adding water to cement.
• Determined by adiabatic calorimeter test or vac-
uum flask test.
• For OPC, heat of hydration at 7 days should not
be more than 65 cal/g, and at 28 days should not
more than 75 cal/g.
6. Specific gravity:
• Determined through test conducted—using kero-
sene and specific gravity bottle at 27° temperature.
• Specific gravity for OPC is about 3.1.
Some Important Specifications—OPC
Fineness (cm
2
/gm) 2250 minimum
Setting times
Initial 30 hours duration
Final 10 hours maximum
Specific gravity 3.1
Compressive strength (kg/cm
2
)
3 days 230 minimum
7 days 330 minimum
28 days 430 minimum
Part III_Unit 4_Chapter 01.indd 255 5/20/2017 7:25:32 PM
Aggregates
• Aggregates are the inert or chemically inactive materials,
which are considered to be as important constituents in
concrete.
• The aggregates may be classified as natural and artificial
aggregates based on source of the aggregates.
• Examples for natural aggregates include sand, gravel,
crushed-rock such as granite, quartz, basalt, sand stone,
etc. Similarly, examples for artificial aggregates include
broken-brick, slag, bloated clay, sintered fly ash, etc.
Properties of Aggregates
1. Size: On the basis of size, these are classified into two
categories. These are:
(a) Fine aggregates
(b) Coarse aggregates
The size of aggregate bigger than 4.75 mm is
considered as coarse aggregate. The size of aggregate
whose size is 4.75 mm and less is considered as fine
aggregate. The maximum size of aggregate should
be as large as possible within the specified limits,
but in any case not greater than
1
4
of the minimum
thickness of the member.
2. Shape: Since shape of aggregate affects the
workability of concrete, it is considered to be an
important characteristic of aggregate.
• Rounded aggregates are preferable to angular
aggregates for a given water cement ratio.
• In contrast, angular aggregates exhibits bet-
ter interlocking effect, higher bond strength than
rounded aggregates which makes this suitable for
roads and pavements construction.
3. Texture: Rough textured aggregate develops higher
bond strength in tension than smooth textured
aggregate.
Tests on Aggregates
Aggregate Crushing Value
• Aggregate crushing value gives a relative measure of
‘resistance of an aggregate to crushing under gradually
applied compressive load.’
• The crushing value of aggregate is restricted to 30% for
concrete used for roads and pavements and 45% may be
permitted for other structures.
Aggregate Impact Value
• Measures toughness of aggregate.
• Toughness is usually considered as the ‘resistance of the
material to failure by impact.’
• Aggregate impact value shall not exceed 45% by weight
for aggregate used for concrete other than wearing surface
and 30% by weight for concrete for wearing surfaces,
such as runways, roads and pavements.
Aggregate Abrasion Test
• Measures hardness or ‘resistance against wear’, which is
important for aggregates to be used for road and pave-
ment construction.
• Common tests to measure abrasion resistance are:
(a) Deval attrition test
(b) Dorry abrasion test
(c) Los Angels test
Bulking of Aggregates
• Free moisture content in fine aggregate results in bulking
of volume.
• Free moisture forms a film around each particle, and this
film exerts surface tension which causes the bulking of
sand.
Flakiness Index
• It is the % by weight of particles in it whose least dimen-
sion (thickness) is less than three-fifths of their mean
dimension.
• This test is not applicable to sizes smaller than 6.3 mm.
Elongation Index
• It is the % by weight of particles whose greatest dimension
(length) is greater than 1.8 times their mean dimension.
• This test is also not applicable to sizes smaller than
6.3 mm.
Specific Gravity and Water Absorption
• Test methods for determining these properties are based
on ‘archimedes principle’.
• Specific gravity =
-
C
BA
• Apparent specific gravity =
-
C
CA
• Water absorption =
- 100( ) BC
C
Where
A = Weight (in g) of saturated aggregate in water
B = Weight (in g) of saturated surface dry aggregate in air
C = Weight (in g) of oven-dried aggregate in air
• Specific gravity for aggregates commonly used in con-
struction varies between 2.5–3.
• Water absorption is generally regarded as measure of
‘porosity’ and it varies from 0.1–2 per cent.
Stripping Value Test
• Also known as ‘bitumen affinity’ test and is carried out to
know the behaviour of aggregates towards bitumen.
Part III_Unit 4_Chapter 01.indd 256 5/20/2017 7:25:33 PM
Page 5
Cement
Chemical Composition
Ordinary cement contains two basic ingredients, namely,
argillaceous and calcareous. In argillaceous materials,
clay predominates and in calcareous calcium carbonate
predominates.
Broadly, the raw materials used for manufacture of
cement consist mainly of lime, silica, alumina and iron
oxide. These oxides interact with one another at high tem-
perature and form more complex compounds. The relative
proportions of these oxide compounds are responsible for
influencing the various properties of cement, in addition to
rate of cooling and fineness of grinding.
Approximate oxide composition ranges for ordinary
portland cement (OPC) are:
Ingredient Chemical Formula Range (%)
Lime CaO 62–67
Silica SiO
2
17–25
Alumina Al
2
O
3
3–8
Calcium Sulphate CaSO
4
3–4
Iron oxide Fe
2
O
3
3–4
Magnesia MgO 1–3
Sulphur S 1–3
Alkalies – 0.2–1
Functions of Cement Ingredients
1. Lime (CaO): Excess lime makes the cement unsound
and causes the cement to expand and disintegrate.
Deficiency in lime makes loss of strength and makes
cement to set quickly.
2. Silica (SiO
2
): SiO
2
imparts the strength to cement
by forming the di-calcium and tri-calcium silicates.
Excess silica makes the strength of cement increases,
but prolongs the setting time.
3. Alumina (Al
2
O
3
): Al
2
O
3
imparts quick setting
property to the cement. It acts as a flux and lowers
the clinkering temperature. Excess alumina makes
cement weaker.
4. Calcium Sulphate (CaSO
4
): It is in the form of
gypsum and increases the initial setting time of
cement.
5. Iron Oxide (Fe
2
O
3
): Fe
2
O
3
imparts colour, hardness
and strength to cement.
6. Magnesia (MgO): MgO imparts hardness and
colour, if present in small amount. Excess MgO
makes cement unsound.
7. Sulphur (S): It is useful in making sound cement.
8. Alkalis: Most of the alkalis present in raw materials are
carried away by the flue gases during heating process.
Presence of alkalis causes problems such as alkali-
aggregate reaction, efflorescence and staining, etc.
Concrete and Its Constituents
Part III_Unit 4_Chapter 01.indd 253 5/20/2017 7:25:32 PM
The above mentioned constituents in chemical reactions
form the following compounds, called ‘bogue’ s compounds’.
Tri-calcium silicate (Alite) C
3
S 45%
Di-calcium silicate (Belite) C
2
S 25%
Tri-calcium Aluminate (celite) C
3
A 11%
Tetra-calcium Alumino Ferrite (Felite) C
4
AF 9%
The functions of each of these compounds are as follows:
1. C
3
S
• Hydrates quickly and contributes more to the early
strength.
• High heat of hydration.
2. C
2
S
• Strengthen the concrete from 7days – 1 year.
• Less heat of hydration.
• Initial setting of cement.
3. C
3
A
• Small contribution to the strength within first 24 hours.
• Very high heat of hydration.
4. C
4
AF
• Comparatively inactive.
Types of Cements
1. Ordinary portland cement (OPC):
• OPC is used in general concrete construction
where there is no exposure to sulphates in soil or
in groundwater.
• Initial and final setting times are 30 minutes and
10 hours.
Different Grades of Ordinary Portland Cement (OPC)
Grade of
Cement
Details
33 grade
ordinary
portland
cement
(IS:269-
1998)
• The compressive strength after 28 days
is 33 N/mm
2
.
• Used for general construction works in
normal environmental conditions.
• Cannot be used where higher grade
concrete above M20 is required.
43 grade
ordinary
portland
cement
(IS:8112-
2000)
• Minimum 28 days compressive strength
43 N/mm
2
.
• Used for construction of residential,
commercial and industrial building, roads,
bridges, flyovers, irrigation projects and
other general civil construction works.
• Suitable for all types of applications
RCC, plastering, masonry, etc.
53 grade
ordinary
portland
cement
(IS:12269-
1999)
• Minimum 28 days compressive strength
53 N/mm
2
.
• Gives 10–15% saving in cement
consumption and 5–8% saving in steel
consumption provided higher grades of
concrete, say M30 and above.
• Useful for high-rise buildings, bridges, flyo-
ver, chimneys and pre-stressed structures
where high-grade concrete is required.
• Gives better durability characteristics to
concrete.
2. Rapid hardening cement:
• Contains high percentage of C
3
S to the extent
about 56%.
• 3 days strength is equivalent to 7 days strength of
OPC.
• Initial and final setting times are as same as OPC.
Advantages:
• Sets rapidly and requires a short period of curing.
• Early removal of formwork.
3. Extra rapid hardening cement:
• Imparts strength about 25% higher than that of
rapid hardening cement.
• It is obtained by inter-grinding calcium chloride
(CaCl
2
) with rapid hardening of portland cement.
4. Low heat cement:
• Contains lower % of C
3
A of about 5% and higher %
of C
2
S about 46%.
• Initial setting time is about an hour and final setting
time is about 10 hours.
• Mainly used for mass concrete works.
5. Hydrophobic cement:
• Contains admixtures which decrease the wetting
ability of cement grains.
• Frost resistance and water resistance of concrete
can be increased by using this type of cement.
• Examples for hydrophobic admixtures includes oleic
acid, oxidized petroleum, naphthalene, soap, etc.
6. Quick setting cement:
• Produced by adding small percentage of alumin-
ium sulphate and by finely grinding the cement.
• Setting action starts within 5 minutes after addition
of water and within 30 minutes it hardens.
• Used to lay concrete under water.
7. Expanding cement:
• Produced by adding an expanding medium like
sulpho-aluminate and a stabilizing agent to OPC.
• Used for repairing damaged concrete surfaces and
for construction of water retaining structures.
8. High alumina cement:
• Produced by grinding clinkers formed by calcined
bauxite and lime.
• Initial setting time is more than 3
1
2
hours and final
setting time is about 5 hours.
• Acid resistant, but high heat of hydration.
9. Pozzolana cement:
• Pozzolana is a silicacious material which has no
cementitious properties when it is used alone, but
in the presence of cement it posses cementitious
properties.
• Pozzolana materials should be between 10–30%.
• Fly ash, blast furanace slag, silica fume are exam-
ples for artificial pozzolans and burnt clay, pumic-
ite are examples for natural pozzolana materials.
Part III_Unit 4_Chapter 01.indd 254 5/20/2017 7:25:32 PM
• Used to prepare mass concrete of lean mix and for
marine works sewage works and for laying con-
crete under water.
10. White cement and coloured cement:
• Used for finishing, plastering and architectural,
and ornamental works.
• Colouring agents, such as iron oxide, cobalt, man-
ganese dioxide, etc., are added to white cement
to obtain red and yellow, blue and black colour
cements.
Tests on Cement
Field Tests
Carried out to roughly ascertain the quality of cement.
1. Colour:
• Should be uniform and in grey colour with light
greenish shade.
• Gives an indication of excess lime or clay and the
degree of burning.
2. Physical properties:
• Should feel smooth when rubbed between fingers.
• It should sink, but not float when small quantity of
cement thrown in a bucket.
• Should feel cool and not warm when hand is
inserted in a bag/heap of cement.
3. Presence of lumps:
• Should be free from any hard lumps.
Laboratory Tests
1. Fineness:
• Carried out to check proper grinding of cement.
• Determined either by sieve test or by permeability
apparatus test.
• In permeability test, ‘specific surface area’ is cal-
culated as a measure of frequency of the average
size of particles, expressed in cm
2
/g.
• It should not be less than 2250 cm
2
/g for OPC,
3250 cm
2
/gm for rapid hardening and 3200 cm
2
/
gm for low heat cements.
2. Consistency:
• To determine the % of water required for making
workable cement paste.
• Apparatus used: Vicat’ s apparatus with Vicat plunger
of 1 cm diameter.
• As per Vicat’s test, percentage of water added
to cement at which the needle penetration is in
between 5–7 mm (from the bottom of the mould)
is called ‘consistency’.
• For OPC, consistency is around 30%.
3. Setting times:
Initial setting time: Determined by Vicat’ s apparatus
using Vicat’ s needle of 1 mm squared needle.
• Water added to cement is about 0.85 times the
water required for standard consistency. Weight of
the cement taken is 300 g to carry out this test.
• Period elapsing between the time when water is
added to the cement and the time at which the nee-
dle fails to pierce the test block by 5 ± 0.5 mm is
taken as the initial setting time.
• For OPC, it should not be less than 30 minutes.
For low heat cements, it should not be less than 60
minutes.
Final setting time: Determined by Vicat’s apparatus
using Vicat’s needle with annual collar of 5 mm
diameter.
• Time lapsed since addition of water to time at
which needle with annual collar can only make a
mark on hard concrete surface, but not piercing is
taken as final setting time.
• It should not be more than 10 hours for OPC.
4. Soundness:
• Soundness refer to the ability of cement to main-
tain constant volume.
• Carried out to detect the presence of un-combined
lime in cement.
• Determined by Le Chatelier apparatus, or Autoclave
test.
• Le Chatelier’s method measures expansion due to
lime, and Autoclave method measures expansion
due to magnesia.
• Expansion more than 10 mm indicates unsound-
ness of cement.
5. Heat of hydration:
• Hydration is the process of adding water to cement.
• Determined by adiabatic calorimeter test or vac-
uum flask test.
• For OPC, heat of hydration at 7 days should not
be more than 65 cal/g, and at 28 days should not
more than 75 cal/g.
6. Specific gravity:
• Determined through test conducted—using kero-
sene and specific gravity bottle at 27° temperature.
• Specific gravity for OPC is about 3.1.
Some Important Specifications—OPC
Fineness (cm
2
/gm) 2250 minimum
Setting times
Initial 30 hours duration
Final 10 hours maximum
Specific gravity 3.1
Compressive strength (kg/cm
2
)
3 days 230 minimum
7 days 330 minimum
28 days 430 minimum
Part III_Unit 4_Chapter 01.indd 255 5/20/2017 7:25:32 PM
Aggregates
• Aggregates are the inert or chemically inactive materials,
which are considered to be as important constituents in
concrete.
• The aggregates may be classified as natural and artificial
aggregates based on source of the aggregates.
• Examples for natural aggregates include sand, gravel,
crushed-rock such as granite, quartz, basalt, sand stone,
etc. Similarly, examples for artificial aggregates include
broken-brick, slag, bloated clay, sintered fly ash, etc.
Properties of Aggregates
1. Size: On the basis of size, these are classified into two
categories. These are:
(a) Fine aggregates
(b) Coarse aggregates
The size of aggregate bigger than 4.75 mm is
considered as coarse aggregate. The size of aggregate
whose size is 4.75 mm and less is considered as fine
aggregate. The maximum size of aggregate should
be as large as possible within the specified limits,
but in any case not greater than
1
4
of the minimum
thickness of the member.
2. Shape: Since shape of aggregate affects the
workability of concrete, it is considered to be an
important characteristic of aggregate.
• Rounded aggregates are preferable to angular
aggregates for a given water cement ratio.
• In contrast, angular aggregates exhibits bet-
ter interlocking effect, higher bond strength than
rounded aggregates which makes this suitable for
roads and pavements construction.
3. Texture: Rough textured aggregate develops higher
bond strength in tension than smooth textured
aggregate.
Tests on Aggregates
Aggregate Crushing Value
• Aggregate crushing value gives a relative measure of
‘resistance of an aggregate to crushing under gradually
applied compressive load.’
• The crushing value of aggregate is restricted to 30% for
concrete used for roads and pavements and 45% may be
permitted for other structures.
Aggregate Impact Value
• Measures toughness of aggregate.
• Toughness is usually considered as the ‘resistance of the
material to failure by impact.’
• Aggregate impact value shall not exceed 45% by weight
for aggregate used for concrete other than wearing surface
and 30% by weight for concrete for wearing surfaces,
such as runways, roads and pavements.
Aggregate Abrasion Test
• Measures hardness or ‘resistance against wear’, which is
important for aggregates to be used for road and pave-
ment construction.
• Common tests to measure abrasion resistance are:
(a) Deval attrition test
(b) Dorry abrasion test
(c) Los Angels test
Bulking of Aggregates
• Free moisture content in fine aggregate results in bulking
of volume.
• Free moisture forms a film around each particle, and this
film exerts surface tension which causes the bulking of
sand.
Flakiness Index
• It is the % by weight of particles in it whose least dimen-
sion (thickness) is less than three-fifths of their mean
dimension.
• This test is not applicable to sizes smaller than 6.3 mm.
Elongation Index
• It is the % by weight of particles whose greatest dimension
(length) is greater than 1.8 times their mean dimension.
• This test is also not applicable to sizes smaller than
6.3 mm.
Specific Gravity and Water Absorption
• Test methods for determining these properties are based
on ‘archimedes principle’.
• Specific gravity =
-
C
BA
• Apparent specific gravity =
-
C
CA
• Water absorption =
- 100( ) BC
C
Where
A = Weight (in g) of saturated aggregate in water
B = Weight (in g) of saturated surface dry aggregate in air
C = Weight (in g) of oven-dried aggregate in air
• Specific gravity for aggregates commonly used in con-
struction varies between 2.5–3.
• Water absorption is generally regarded as measure of
‘porosity’ and it varies from 0.1–2 per cent.
Stripping Value Test
• Also known as ‘bitumen affinity’ test and is carried out to
know the behaviour of aggregates towards bitumen.
Part III_Unit 4_Chapter 01.indd 256 5/20/2017 7:25:33 PM
• Aggregates can be classified into 2 categories:
(a) Hydrophilic
(b) Hydrophobic
• Hydrophilic are water liking and they lose their bitumi-
nous coating in presence of water. On the other hand,
hydrophobic retains bituminous coating even in presence
of water.
Angularity Number
• It indicates the amount by which the percentage voids
exceeds 33% after being compacted in prescribed manner.
• Angularity number = 67% solid volume
• The angularity number is expressed to the nearest whole
number, and it ranges for aggregates used in construction
is from 0 to 11.
Admixtures
Admixture is defined as a material other than cement, water
and aggregates, that is used an ingredient of concrete and is
added to batch immediately before or during mixing.
Types of Admixtures
Mineral Admixtures
1. Fly ash
2. Silica fume
3. Ground granulated blast furnace slag (GGBS)
4. Stone powder, etc.
Chemical Admixtures
1. Accelerators:
• Increases the rate of strength development or
reduces the setting time.
• Calcium chloride (CaCl
2
) is widely used
accelerator.
• Other examples include tri-ethenoalamine, fluosili-
cates, etc.
2. Retarders:
• Delays the setting time of cement paste.
Examples: Gypsum (calcium sulphate), mucic
acid, calcium acetate, sugar, etc.
3. Plasticizers (water reducers):
• Increases the workability of concrete without alter-
ing the water/cement ratio.
Examples: Ligno sulphuric acids in form of cal-
cium or sodium salts, oleate, etc.
4. Super plasticizers (high range water reducers):
• Imparts very high workability with large decrease
in water content (at least 20%) for a given
workability.
Examples: Hydroxylated carboxylic acids, for-
maldehyde derivates, such as melamine formalde-
hyde, naphalene sulphonate formaldehyde, etc.
Uses of Admixtures
Admixtures are used to:
1. Accelerate or retard setting times.
2. Decrease heat of evolution, rate of bleeding,
segregation.
3. Increase the rate of hydration and strength
development.
4. Increase water tightness and reduce capillary flow,
etc.
Concrete
Fresh concrete: Fresh concrete or plastic concrete is a
freshly mixed material which can be moulded into any
shape.
Workability
Workability is defined as the property of concrete which
determines the amount of useful internal work necessary to
produce full compaction.
In another words, it is defined as the ‘ease with which
concrete can fully compacted having regard to the mode of
compaction and place of deposition.
The following factors affect the workability of concrete.
Water Content
• Higher the water content, higher will be the fluidity of
concrete.
• It is important to maintain the water and cement ratio
constant while adding water to the concrete, for the pur-
pose of achieving high workability.
Water and cement ratio, more than 0.38, will results in
capillary cavities. A ratio which is less than this will result
in incomplete hydration.
NOTE
Mix Proportions
• Higher the aggregate and cement ratio, leaner the
concrete.
• In lean concrete, less quantity of paste is available for
lubrication per unit surface area of aggregate; hence
mobility of aggregate is restrained.
• On the other hand, lesser the aggregate and cement ratio,
higher the work-ability.
Size and Shape of Aggregate
• Bigger the size of aggregates, higher the workability.
• Angular, elongated, or flaky aggregate makes the con-
crete very harsh when compared to rounded aggregates
or cube-shaped aggregates.
Part III_Unit 4_Chapter 01.indd 257 5/20/2017 7:25:33 PM
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