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In an octahedral structure, the pair of d orbitals involved in d2sp3 hybridization is [2004]
  • a)
  • b)
     
  • c)
    dz2 , dxz
  • d)
    dxy,dyz
Correct answer is option 'A'. Can you explain this answer?
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In an octahedral structure, the pair of d orbitals involved in d2sp3 h...
Only those d or bital s whose  l obes are directed along X, Y and Z directions hybridise with s and p orbitals. In other three d or bitals n amely dxy, dyz and dxz, the lobes are at an angle of 45° from both axis, hence the extent of their overlap with s and p orbitals is much lesser than and orbitals.
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In an octahedral structure, the pair of d orbitals involved in d2sp3 h...
Octahedral structure and d2sp3 hybridization

Octahedral structure

An octahedral structure is a molecular geometry in which six atoms or groups of atoms are symmetrically arranged around a central atom, forming the shape of an octahedron. This structure is commonly found in coordination compounds, where a central metal ion is surrounded by six ligands.

d2sp3 hybridization

In octahedral coordination compounds, the central metal ion usually has a coordination number of six, which means it is surrounded by six ligands. In order to form six bonds, the metal ion must use its d orbitals in addition to its s and p orbitals. The hybridization of these orbitals is called d2sp3 hybridization.

Pair of d orbitals involved in d2sp3 hybridization

In d2sp3 hybridization, two of the d orbitals combine with the s and p orbitals to form four hybrid orbitals, which are arranged in an octahedral geometry. The other two d orbitals remain unhybridized and are oriented along the z-axis and the x-axis, respectively.

The pair of d orbitals involved in d2sp3 hybridization is thus:

- dx2-y2: This orbital lies along the x-axis and the y-axis and has four lobes pointing toward the corners of a square.
- dz2: This orbital lies along the z-axis and has a doughnut-shaped electron density distribution above and below the metal ion.

Therefore, the correct answer is option A, dx2-y2 and dz2.
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