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50 mL of each gas A and of gas B takes 150 and 200 seconds respectively for effusing through a pin hole under the similar condition. If molecular mass of gas B is 36, the molecular mass of gas A will be : [2012]

  • a)
    96

  • b)
    128

  • c)
    20.2

  • d)
    64

Correct answer is option 'C'. Can you explain this answer?
Verified Answer
50 mL of each gas A and of gas B takes 150 and 200 seconds respectivel...
So, most approximate answer is 32
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Most Upvoted Answer
50 mL of each gas A and of gas B takes 150 and 200 seconds respectivel...
Given, time taken for gas A to effuse through a pinhole = 150 seconds
time taken for gas B to effuse through a pinhole = 200 seconds
molecular mass of gas B = 36

Effusion rate of a gas is inversely proportional to the square root of its molecular mass. Therefore, the ratio of the effusion rates of gases A and B can be written as:

effusion rate of A/effusion rate of B = sqrt (molecular mass of B/ molecular mass of A)

Let's assume the molecular mass of gas A to be x.

So we have,

effusion rate of A/effusion rate of B = sqrt (36/x)

150/200 = sqrt (36/x)

3/4 = 6/sqrt(x)

sqrt(x) = 24

x = (24)^2 = 576/1 = 576

Therefore, the molecular mass of gas A is 576/1 = 576 amu.

But, as we know that the molecular mass of a gas cannot be this high, we need to convert amu to g/mol.

1 amu = 1.66 x 10^-24 g

Therefore, the molecular mass of gas A in g/mol is:

576 amu x (1.66 x 10^-24 g/amu) x (6.02 x 10^23/mol) = 20.2 g/mol

Hence, the correct answer is option C.
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50 mL of each gas A and of gas B takes 150 and 200 seconds respectively for effusing through a pin hole under the similar condition. If molecular mass of gas B is 36, the molecular mass of gas A will be : [2012]a)96b)128c)20.2d)64Correct answer is option 'C'. Can you explain this answer?
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