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The number of moles of KMnO4 that will be needed to react with one mole of sulphite ion in acidic solution is [2007]
  • a)
    4/5
  • b)
    2/5
  • c)
    1
  • d)
    3/5
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
The number of moles of KMnO4 that will be needed to react with one mol...
The balance chemical equation is :
From the equation it is clear that Moles of MnO4 require to oxidise 5 moles of SO3 are 2
Moles of MnO4 require to oxidise 1 mole of SO3– – are 2/5.
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The number of moles of KMnO4 that will be needed to react with one mol...
Acidic solution means the medium in which the reaction takes place is acidic. The reaction between KMnO4 and sulphite ion in acidic medium can be represented as follows:

5 SO32- + 2 MnO4- + 6 H+ → 5 SO42- + 2 Mn2+ + 3 H2O

From the balanced equation, it is clear that 2 moles of KMnO4 are required to react with 5 moles of sulphite ion in acidic solution. Therefore, the number of moles of KMnO4 that will be needed to react with one mole of sulphite ion in acidic solution is:

2 moles KMnO4 / 5 moles SO32- = 0.4 moles KMnO4 / 1 mole SO32-

Therefore, the correct answer is option B, 2/5.
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The number of moles of KMnO4 that will be needed to react with one mole of sulphite ion in acidic solution is [2007]a)4/5b)2/5c)1d)3/5Correct answer is option 'B'. Can you explain this answer?
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