The probable formula for prussian blue is: a)Fe3[Fe(CN)6]2 b)Fe2[Fe(C...
Ferric ferricyanide.
Fe+3 ( ferric)outside the coordination sphere and Fe+2 (Ferro) inside. On putting these Oxidation states, only formula that satisfies this is D.
HENCE, rest can easily be eliminated.
only thing you need to remember is Ferric Ferrocyanide.
The probable formula for prussian blue is: a)Fe3[Fe(CN)6]2 b)Fe2[Fe(C...
Prussian Blue Formula
Prussian blue is a dark blue pigment that has the chemical formula Fe3[Fe(CN)6]4. Let's break down the formula and understand its composition.
Iron (Fe)
- Prussian blue is primarily composed of iron (Fe) ions. In this compound, there are multiple iron ions present.
Cyanide (CN)
- Cyanide (CN) is a polyatomic ion that consists of one carbon atom (C) and one nitrogen atom (N). In the formula of Prussian blue, cyanide ions are present.
Prussian Blue Formula Breakdown
- Prussian blue has the formula Fe3[Fe(CN)6]4. Let's break it down further:
1. Fe3: This indicates that there are three iron ions present in the compound.
2. [Fe(CN)6]4: This represents a complex ion formed by one iron ion (Fe) bonded to six cyanide ions (CN). The 4 denotes that there are four of these complex ions.
Explanation of Correct Answer (Option D)
The correct formula for Prussian blue is Fe3[Fe(CN)6]4, which is denoted by option D.
Option A (Fe3[Fe(CN)6]2) is incorrect because it suggests that there are only two complex ions of [Fe(CN)6], whereas the correct formula indicates four.
Option B (Fe2[Fe(CN)6]3) is incorrect because it suggests that there are three complex ions of [Fe(CN)6], whereas the correct formula indicates four.
Option C (Fe4[Fe(CN)6]3) is incorrect because it suggests that there are three complex ions of [Fe(CN)6], whereas the correct formula indicates four.
Therefore, the correct formula for Prussian blue is Fe3[Fe(CN)6]4, as indicated in option D.