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[Co(NH3)4 (NO2)2] Cl exhibits [2006]
- a)linkage isomerism, ionization isomerism and geometrical isomerism
- b)ionization isomerism, geometrical isomerism and optical isomerism
- c)linkage isomerism, geometrical isomerism and optical isomerism
- d)linkage isomerism, ionization isomerism and optical isomerism
Correct answer is option 'A'. Can you explain this answer?
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Verified Answer
[Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization is...
The given compound may have lin kage isomerism due to presence of NO2 group which may be in the form –NO2 or –ONO.
It may have ionisation isomerism due to presence of two ionisable group –NO2 & – Cl. It may have geometrical isomerism in the form of form as follows :
It may have ionisation isomerism due to presence of two ionisable group –NO2 & – Cl. It may have geometrical isomerism in the form of form as follows :
Geometrical isomers
Most Upvoted Answer
[Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization is...
Explanation:
In the complex [Co(NH3)4(NO2)2]Cl, the central cobalt ion is coordinated to four ammonia (NH3) ligands and two nitrite (NO2) ligands. The chloride ion (Cl-) acts as a counterion to balance the charge of the complex.
The different types of isomerism observed in this complex are as follows:
1. Linkage isomerism:
In linkage isomerism, the ligand can coordinate to the central metal ion through different atoms. In this complex, the nitrite ligand (NO2-) can coordinate to the cobalt ion through either the nitrogen atom (N-bound) or the oxygen atom (O-bound). Therefore, the complex can exist in two different forms:
- [Co(NH3)4(NO2)2]Cl (N-bound)
- [Co(NH3)4(ONO)]Cl (O-bound)
2. Ionization isomerism:
In ionization isomerism, the ligands and counterions exchange places. In this complex, the chloride ion (Cl-) and the nitrite ligand (NO2-) can exchange places. Therefore, the complex can exist in two different forms:
- [Co(NH3)4(NO2)2]Cl (nitrite ligand coordinated)
- [Co(NH3)4(NO2)2]NO2 (chloride ion coordinated)
3. Geometrical isomerism:
In geometrical isomerism, the ligands can be arranged in different spatial orientations around the central metal ion. In this complex, the four ammonia ligands (NH3) can be either arranged in a cis configuration or a trans configuration. Therefore, the complex can exist in two different forms:
- cis-[Co(NH3)4(NO2)2]Cl
- trans-[Co(NH3)4(NO2)2]Cl
Conclusion:
From the above explanations, it can be concluded that the complex [Co(NH3)4(NO2)2]Cl exhibits linkage isomerism (N-bound and O-bound), ionization isomerism (nitrite ligand coordinated and chloride ion coordinated), and geometrical isomerism (cis and trans configurations). Therefore, the correct answer is option 'A' - linkage isomerism, ionization isomerism, and geometrical isomerism.
In the complex [Co(NH3)4(NO2)2]Cl, the central cobalt ion is coordinated to four ammonia (NH3) ligands and two nitrite (NO2) ligands. The chloride ion (Cl-) acts as a counterion to balance the charge of the complex.
The different types of isomerism observed in this complex are as follows:
1. Linkage isomerism:
In linkage isomerism, the ligand can coordinate to the central metal ion through different atoms. In this complex, the nitrite ligand (NO2-) can coordinate to the cobalt ion through either the nitrogen atom (N-bound) or the oxygen atom (O-bound). Therefore, the complex can exist in two different forms:
- [Co(NH3)4(NO2)2]Cl (N-bound)
- [Co(NH3)4(ONO)]Cl (O-bound)
2. Ionization isomerism:
In ionization isomerism, the ligands and counterions exchange places. In this complex, the chloride ion (Cl-) and the nitrite ligand (NO2-) can exchange places. Therefore, the complex can exist in two different forms:
- [Co(NH3)4(NO2)2]Cl (nitrite ligand coordinated)
- [Co(NH3)4(NO2)2]NO2 (chloride ion coordinated)
3. Geometrical isomerism:
In geometrical isomerism, the ligands can be arranged in different spatial orientations around the central metal ion. In this complex, the four ammonia ligands (NH3) can be either arranged in a cis configuration or a trans configuration. Therefore, the complex can exist in two different forms:
- cis-[Co(NH3)4(NO2)2]Cl
- trans-[Co(NH3)4(NO2)2]Cl
Conclusion:
From the above explanations, it can be concluded that the complex [Co(NH3)4(NO2)2]Cl exhibits linkage isomerism (N-bound and O-bound), ionization isomerism (nitrite ligand coordinated and chloride ion coordinated), and geometrical isomerism (cis and trans configurations). Therefore, the correct answer is option 'A' - linkage isomerism, ionization isomerism, and geometrical isomerism.
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[Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization isomerism and geometrical isomerismb)ionization isomerism, geometrical isomerism and optical isomerismc)linkage isomerism, geometrical isomerism and optical isomerismd)linkage isomerism, ionization isomerism and optical isomerismCorrect answer is option 'A'. Can you explain this answer?
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[Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization isomerism and geometrical isomerismb)ionization isomerism, geometrical isomerism and optical isomerismc)linkage isomerism, geometrical isomerism and optical isomerismd)linkage isomerism, ionization isomerism and optical isomerismCorrect answer is option 'A'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about [Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization isomerism and geometrical isomerismb)ionization isomerism, geometrical isomerism and optical isomerismc)linkage isomerism, geometrical isomerism and optical isomerismd)linkage isomerism, ionization isomerism and optical isomerismCorrect answer is option 'A'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for [Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization isomerism and geometrical isomerismb)ionization isomerism, geometrical isomerism and optical isomerismc)linkage isomerism, geometrical isomerism and optical isomerismd)linkage isomerism, ionization isomerism and optical isomerismCorrect answer is option 'A'. Can you explain this answer?.
[Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization isomerism and geometrical isomerismb)ionization isomerism, geometrical isomerism and optical isomerismc)linkage isomerism, geometrical isomerism and optical isomerismd)linkage isomerism, ionization isomerism and optical isomerismCorrect answer is option 'A'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about [Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization isomerism and geometrical isomerismb)ionization isomerism, geometrical isomerism and optical isomerismc)linkage isomerism, geometrical isomerism and optical isomerismd)linkage isomerism, ionization isomerism and optical isomerismCorrect answer is option 'A'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for [Co(NH3)4 (NO2)2] Cl exhibits [2006]a)linkage isomerism, ionization isomerism and geometrical isomerismb)ionization isomerism, geometrical isomerism and optical isomerismc)linkage isomerism, geometrical isomerism and optical isomerismd)linkage isomerism, ionization isomerism and optical isomerismCorrect answer is option 'A'. Can you explain this answer?.
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