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Among the following  the electron deficient compound is : [2000]

  • a)
    BCl3

  • b)
    CCl4

  • c)
    PCl5

  • d)
    SiF4

Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Among the following the electron deficient compound is : [2000]a)BCl3b...
In BCl3​ the valence electrons for boron are 6 (3 of boron and 3 of chlorine), so there are two electrons deficient for the octet configuration. Thus, electron deficient molecule is BCl3​.
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Among the following the electron deficient compound is : [2000]a)BCl3b...
Electron Deficient Compound:
An electron deficient compound is one that lacks sufficient electrons to complete its valence shell. These compounds typically have an incomplete octet or less than eight valence electrons around the central atom.

Analysis of Options:
a) BCl3: Boron (B) has three valence electrons, and each chlorine (Cl) atom contributes one electron. Therefore, BCl3 has a total of six valence electrons. It is an electron deficient compound as it lacks two electrons to complete its octet.

b) CCl4: Carbon (C) has four valence electrons, and each chlorine (Cl) atom contributes one electron. Therefore, CCl4 has a total of eight valence electrons, fulfilling the octet rule. It is not an electron deficient compound.

c) PCl5: Phosphorus (P) has five valence electrons, and each chlorine (Cl) atom contributes one electron. Therefore, PCl5 has a total of ten valence electrons, exceeding the octet rule. It is not an electron deficient compound.

d) SiF4: Silicon (Si) has four valence electrons, and each fluorine (F) atom contributes one electron. Therefore, SiF4 has a total of eight valence electrons, fulfilling the octet rule. It is not an electron deficient compound.

Conclusion:
Among the given options, BCl3 is the only compound that is electron deficient. It lacks two electrons to complete its valence shell and satisfy the octet rule. Therefore, the correct answer is option 'A' - BCl3.
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