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Which of the following will give a pair of enantiomorphs? [2007]
  • a)
    [Cr(NH3)6][Co(CN)6]
  • b)
    [Co(en)2Cl2]Cl
  • c)
    [Pt(NH3)4] [PtCl6]
  • d)
    [Co(NH3)4Cl2]NO2. (en =NH2CH2CH2NH2)
Correct answer is option 'B'. Can you explain this answer?
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Which of the following will give a pair of enantiomorphs? [2007]a)[Cr(...
Non superimposable mirror images are called optical isomers and may be described as “chiral’. They are also called enantiomers and rotate plane polarised light in opposite directions.
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Which of the following will give a pair of enantiomorphs? [2007]a)[Cr(...
Explanation:

Enantiomers are stereoisomers that are non-superimposable mirror images of each other. In order for a pair of compounds to be enantiomers, they must have the same connectivity of atoms but differ in their three-dimensional arrangement.

Let's analyze each option to determine which one will give a pair of enantiomorphs.

a) [Cr(NH3)6][Co(CN)6]
- This compound consists of two different coordination complexes, the hexammine chromium(III) ion [Cr(NH3)6]3+ and the hexacyanocobaltate(III) ion [Co(CN)6]3-. These complexes do not have the same connectivity of atoms, so they cannot be enantiomers.

b) [Co(en)2Cl2]Cl
- This compound contains the coordination complex [Co(en)2Cl2]+, where en is the ethylenediamine ligand. The two en ligands are bonded to the central cobalt atom in a chelating arrangement, forming a five-membered chelate ring. The chlorine atoms are in a cis configuration. If we imagine swapping the positions of the two en ligands, we will obtain the enantiomer of the complex. Therefore, this compound can exist as a pair of enantiomers.

c) [Pt(NH3)4][PtCl6]
- This compound consists of two different coordination complexes, the tetraammine platinum(II) ion [Pt(NH3)4]2+ and the hexachloroplatinate(IV) ion [PtCl6]2-. These complexes do not have the same connectivity of atoms, so they cannot be enantiomers.

d) [Co(NH3)4Cl2]NO2
- This compound contains the coordination complex [Co(NH3)4Cl2]+, where four ammonia ligands and two chloride ligands are bonded to the central cobalt atom. The nitrite ion NO2- is not a ligand in this complex. Therefore, this compound does not have the same connectivity of atoms as the compound in option b, so they cannot be enantiomers.

Conclusion:
The correct answer is option b) [Co(en)2Cl2]Cl, which can exist as a pair of enantiomers by swapping the positions of the two ethylenediamine ligands.
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Which of the following will give a pair of enantiomorphs? [2007]a)[Cr(NH3)6][Co(CN)6]b)[Co(en)2Cl2]Clc)[Pt(NH3)4] [PtCl6]d)[Co(NH3)4Cl2]NO2. (en =NH2CH2CH2NH2)Correct answer is option 'B'. Can you explain this answer? for Class 12 2025 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Which of the following will give a pair of enantiomorphs? [2007]a)[Cr(NH3)6][Co(CN)6]b)[Co(en)2Cl2]Clc)[Pt(NH3)4] [PtCl6]d)[Co(NH3)4Cl2]NO2. (en =NH2CH2CH2NH2)Correct answer is option 'B'. Can you explain this answer? covers all topics & solutions for Class 12 2025 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following will give a pair of enantiomorphs? [2007]a)[Cr(NH3)6][Co(CN)6]b)[Co(en)2Cl2]Clc)[Pt(NH3)4] [PtCl6]d)[Co(NH3)4Cl2]NO2. (en =NH2CH2CH2NH2)Correct answer is option 'B'. Can you explain this answer?.
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