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Mark the correct statement [1985]
  • a)
    Methylamine is slightly acidic
  • b)
    Methylamine is less basic than ammonia
  • c)
    Methylamine is a stronger base thanammonia
  • d)
    Methylamine forms salts with alkalies.
Correct answer is option 'C'. Can you explain this answer?
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Verified Answer
Mark the correct statement [1985]a)Methylamine is slightly acidicb)Met...
Methyl amine is a stronger base than
ammonia due to +I effect. The alkyl groups
which are electron releasing groups increase
the electron density around the nitrogen
thereby increasing the availability of the lone
pair of electrons to proton or lewis acid and
making the amine more basic
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Most Upvoted Answer
Mark the correct statement [1985]a)Methylamine is slightly acidicb)Met...

Explanation:

Methylamine vs Ammonia:
Methylamine (CH3NH2) is a derivative of ammonia (NH3) where one hydrogen atom is replaced by a methyl group (CH3). In terms of basicity, methylamine is a stronger base than ammonia.

Basicity Comparison:
Methylamine is more basic than ammonia due to the presence of the methyl group, which donates electron density to the nitrogen atom, making it more available for accepting a proton. This increased electron density enhances the basicity of methylamine compared to ammonia.

Formation of Salts:
Methylamine can form salts with acids as it can act as a base by accepting a proton. This property allows methylamine to react with acids to form salts, similar to how ammonia behaves in salt formation reactions.

Therefore, the correct statement is:
c) Methylamine is a stronger base than ammonia.
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Read the passage given below and answer the following questions:Greater is the stability of the substituted ammonium cation, stronger should be the corresponding amine as a base. Thus, the order of basicity of aliphatic amines should be: primary > secondary > tertiary, which is opposite to the inductive effect based order. Secondly, when the alkyl group is small, like –CH3 group, there is no steric hindrance to H-bonding. In case the alkyl group is bigger than CH3 group, there will be steric hinderance to H-bonding. Therefore, the change of nature of the alkyl group, e.g., from –CH3 to –C2H5 results in change of the order of basic strength.In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.Assertion (

Mark the correct statement [1985]a)Methylamine is slightly acidicb)Methylamine is less basic than ammoniac)Methylamine is a stronger base thanammoniad)Methylamine forms salts with alkalies.Correct answer is option 'C'. Can you explain this answer?
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