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Pure nitrogen is prepared in the laboratory by heating a mixture of [1991]
  • a)
    NH4OH + NaCl
  • b)
    NH4 NO3 + NaCl
  • c)
    NH4 Cl + NaOH
  • d)
    NH4 Cl + NaNO2.
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
Pure nitrogen is prepared in the laboratory by heating a mixture of [1...
Pure nitrogen in the lab can be obtained by heating ammonium nitrate. Ammonium nitrate is not a stable compound it dissociate to give nitrogen.
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Most Upvoted Answer
Pure nitrogen is prepared in the laboratory by heating a mixture of [1...
Explanation:

Nitrogen gas (N2) is prepared in the laboratory by the decomposition of ammonium nitrite (NH4NO2). This can be achieved by heating a mixture of ammonium chloride (NH4Cl) and sodium nitrite (NaNO2).

The reaction involved is:
2NH4Cl + 2NaNO2 → N2 + 2NaCl + 4H2O

Step-by-Step Explanation:

1. Start with a mixture of ammonium chloride (NH4Cl) and sodium nitrite (NaNO2) in a reaction vessel.

2. Heat the mixture to a high temperature, typically around 300-400°C. This provides the energy needed to drive the decomposition reaction.

3. The ammonium chloride (NH4Cl) decomposes into ammonia gas (NH3) and hydrogen chloride gas (HCl) according to the following reaction:
NH4Cl → NH3 + HCl

4. The sodium nitrite (NaNO2) decomposes into sodium nitrate (NaNO3) and nitrogen dioxide gas (NO2) according to the following reaction:
2NaNO2 → 2NaNO3 + N2O

5. The nitrogen dioxide gas (NO2) further decomposes into nitrogen gas (N2) and oxygen gas (O2) according to the following reaction:
2NO2 → 2NO + O2
2NO → N2 + O2

6. The nitrogen gas (N2) is collected and can be used for various applications.

Key Points:
- Pure nitrogen gas (N2) can be prepared in the laboratory by heating a mixture of ammonium chloride (NH4Cl) and sodium nitrite (NaNO2).
- The reaction involves the decomposition of both ammonium chloride and sodium nitrite, resulting in the formation of nitrogen gas, sodium chloride, and water.
- The decomposition reactions are driven by the high temperature provided during the heating process.
- Nitrogen gas is collected and can be used for various purposes.
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