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Which of the following statement is correct?
  • a)
    Ecell and ΔrG of a cell reaction both are extensive properties
  • b)
    Ecell and ΔrG of a cell reaction both are intensive properties
  • c)
    Ecell  is an intensive property while  ΔrG of a cell reaction is an extensive property
  • d)
    Ecell  is an extensive property while  ΔrG of a cell reaction is an intensive property
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
Which of the following statement is correct?a)Ecelland ΔrG of a c...
cell  remains unchanged on division , thus intensive property.
ΔrG is dependent on the division , thus extensive property.
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Most Upvoted Answer
Which of the following statement is correct?a)Ecelland ΔrG of a c...
Ecell and rG are both important thermodynamic properties used to describe the behavior of electrochemical cells. Ecell represents the cell potential or electromotive force (EMF), which is a measure of the driving force for the cell reaction. On the other hand, rG (Gibbs free energy change) represents the thermodynamic driving force for a chemical reaction, including electrochemical reactions.

Ecell is an intensive property because it does not depend on the amount of substance present in the system. It is solely determined by the nature of the reactants and products involved in the cell reaction. Intensive properties are independent of the system's size or the amount of substance present. For example, the cell potential of a half-cell will remain the same regardless of whether it is combined with another half-cell to form a complete cell or if it is used in isolation.

On the other hand, rG is an extensive property because it depends on the amount of substance present in the system. The Gibbs free energy change is directly proportional to the quantity of reactants and products involved in the cell reaction. Extensive properties change with the size or amount of substance present. For example, if the number of moles of reactants and products in a cell reaction is doubled, the value of rG will also double.

Therefore, the correct statement is option C: Ecell is an intensive property while rG of a cell reaction is an extensive property. This means that the cell potential remains the same regardless of the scale of the reaction, while the Gibbs free energy change will vary depending on the amount of substance involved in the reaction.

In summary:
- Ecell (cell potential) is an intensive property, independent of the amount of substance.
- rG (Gibbs free energy change) is an extensive property, dependent on the amount of substance.
- Option C is correct because it correctly distinguishes between the intensive and extensive nature of Ecell and rG.
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Which of the following statement is correct?a)Ecelland ΔrG of a cell reaction both are extensive propertiesb)Ecelland ΔrGof a cell reaction both are intensive propertiesc)Ecell is an intensive property while ΔrGof a cell reaction is an extensive propertyd)Ecell is an extensive property while ΔrGof a cell reaction is an intensive propertyCorrect answer is option 'C'. Can you explain this answer?
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Which of the following statement is correct?a)Ecelland ΔrG of a cell reaction both are extensive propertiesb)Ecelland ΔrGof a cell reaction both are intensive propertiesc)Ecell is an intensive property while ΔrGof a cell reaction is an extensive propertyd)Ecell is an extensive property while ΔrGof a cell reaction is an intensive propertyCorrect answer is option 'C'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Which of the following statement is correct?a)Ecelland ΔrG of a cell reaction both are extensive propertiesb)Ecelland ΔrGof a cell reaction both are intensive propertiesc)Ecell is an intensive property while ΔrGof a cell reaction is an extensive propertyd)Ecell is an extensive property while ΔrGof a cell reaction is an intensive propertyCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following statement is correct?a)Ecelland ΔrG of a cell reaction both are extensive propertiesb)Ecelland ΔrGof a cell reaction both are intensive propertiesc)Ecell is an intensive property while ΔrGof a cell reaction is an extensive propertyd)Ecell is an extensive property while ΔrGof a cell reaction is an intensive propertyCorrect answer is option 'C'. Can you explain this answer?.
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