Find the work performed when 2 moles of hydrogen expand isothermally a...
Solution:
To find the work performed during the isothermal and reversible expansion of 2 moles of hydrogen gas, we can use the following equation:
Work (W) = -nRT ln(Vf/Vi)
Where:
- n is the number of moles of the gas
- R is the ideal gas constant (8.314 J/(mol·K))
- T is the temperature in Kelvin
- Vi is the initial volume
- Vf is the final volume
Given:
- n = 2 moles
- T = 25°C = 298 K
- Vi = 15 L
- Vf = 50 L
Calculating the Work:
Substituting the given values into the equation, we have:
W = -2 * 8.314 J/(mol·K) * 298 K * ln(50 L/15 L)
Simplifying the expression, we get:
W ≈ -2 * 8.314 J/(mol·K) * 298 K * ln(3.33)
W ≈ -2 * 8.314 J/(mol·K) * 298 K * 1.203
W ≈ -5980.6 J
Therefore, the work performed during the isothermal and reversible expansion of 2 moles of hydrogen gas from 15 L to 50 L is approximately -5980.6 J.
Explanation:
- The work performed during the expansion of a gas is given by the equation W = -nRT ln(Vf/Vi).
- In this case, we have 2 moles of hydrogen gas undergoing an isothermal and reversible expansion.
- The ideal gas constant, R, is a constant value.
- The temperature, T, is given as 25°C, which is converted to Kelvin by adding 273 (298 K).
- The initial volume, Vi, is given as 15 L.
- The final volume, Vf, is given as 50 L.
- Substituting these values into the equation, we can calculate the work performed.
- The natural logarithm (ln) of the ratio of final volume to initial volume determines the magnitude and direction of the work.
- The negative sign in the equation indicates that work is done on the system during expansion.
- The final answer is approximately -5980.6 J, indicating that work is done on the system.
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