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Which of the following have dipole moment ?
  • a)
    nitrobenzene
  • b)
    p-chloronitrobenzene
  • c)
    m-dichlorobenzene
  • d)
    o- dichlorobenzene
Correct answer is option 'A,B,C,D'. Can you explain this answer?
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Which of the following have dipole moment ?a)nitrobenzeneb)p-chloronit...
Understanding Dipole Moments
Dipole moments arise in molecules that have a separation of positive and negative charges, resulting from differences in electronegativity between atoms. Let’s analyze each compound listed to determine if they possess a dipole moment.
Nitrobenzene (A)
- Nitrobenzene contains a nitro group (-NO2) that is highly electronegative.
- The electron-withdrawing nature of the nitro group creates a significant dipole moment, making nitrobenzene polar.
p-Chloronitrobenzene (B)
- In p-chloronitrobenzene, both the chlorine atom and the nitro group are present at the para position.
- The electronegativities of chlorine and the nitro group lead to a resultant dipole moment, confirming that this compound is polar.
m-Dichlorobenzene (C)
- m-Dichlorobenzene has two chlorine atoms at the meta position.
- The dipole moments of the two chlorines do not cancel each other out completely, resulting in a net dipole moment for the molecule.
o-Dichlorobenzene (D)
- o-Dichlorobenzene also features two chlorines, but they are positioned ortho to each other.
- Similar to m-dichlorobenzene, the dipole moments from the two chlorines do not completely cancel, leading to a measurable dipole moment.
Conclusion
All four compounds (A, B, C, D) have dipole moments due to the presence of electronegative substituents and their respective arrangements on the benzene ring. Their polar nature is essential in understanding their chemical behavior and interactions.
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Which of the following have dipole moment ?a)nitrobenzeneb)p-chloronitrobenzenec)m-dichlorobenzened)o- dichlorobenzeneCorrect answer is option 'A,B,C,D'. Can you explain this answer?
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