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Which of the following is/are true regarding aldol condensation ?
  • a)
    Both acid and base can act as catalyst
  • b)
    A new carbon-carbon bond is always formed
  • c)
    CH3CHO and D3C—CHO react at same rate if all other conditions are similar
  • d)
    Prqpanal and propanone react at same rate if all other conditions are similar
Correct answer is option 'A,B,C'. Can you explain this answer?
Verified Answer
Which of the following is/are true regarding aldol condensation ?a)Bot...
Both acid and base catalyses aldol reaction. In aldol reaction , a new α - β C—C bond is always formed . α - H is lost in first fast step, hence both CH3CHO and CD3CHO react at the same rate.
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Most Upvoted Answer
Which of the following is/are true regarding aldol condensation ?a)Bot...
**Aldol Condensation**

Aldol condensation is a reaction that involves the combination of two carbonyl compounds (aldehydes or ketones) to form a β-hydroxy carbonyl compound. It is an important reaction in organic chemistry and has several characteristics that are true about it.

**a) Both acid and base can act as a catalyst**

In aldol condensation, both acids and bases can act as catalysts. Acidic conditions favor the formation of enols, which are more reactive than the carbonyl compounds. Acid catalysis involves the protonation of the carbonyl compound, leading to the formation of an enol intermediate. On the other hand, basic conditions favor the formation of the enolate anion, which is also a reactive intermediate. Base-catalyzed aldol condensation involves the deprotonation of the carbonyl compound to form the enolate ion. Therefore, both acid and base can catalyze the aldol condensation reaction.

**b) A new carbon-carbon bond is always formed**

In aldol condensation, a new carbon-carbon bond is always formed. This is the key step in the reaction and is responsible for the formation of the β-hydroxy carbonyl compound. The carbonyl compound acts as a nucleophile and attacks the carbonyl carbon of another carbonyl compound, leading to the formation of the new carbon-carbon bond. This bond formation is what distinguishes aldol condensation from other reactions involving carbonyl compounds.

**c) CH3CHO and D3CCHO react at the same rate if all other conditions are similar**

In aldol condensation, the rate of reaction depends on the reactivity of the carbonyl compounds involved. In general, aldehydes are more reactive than ketones in aldol condensation reactions. However, if all other conditions are similar, such as temperature, solvent, and catalyst, the rate of reaction between CH3CHO and D3CCHO would be expected to be similar. This is because the difference in reactivity between an aldehyde and a ketone is not significant enough to cause a substantial difference in the reaction rate.

**d) Propanal and propanone react at the same rate if all other conditions are similar**

Similarly to the previous point, if all other conditions are similar, the rate of reaction between propanal and propanone would be expected to be similar. Both propanal and propanone are carbonyl compounds, and the difference in reactivity between them is not significant enough to cause a substantial difference in the reaction rate.
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