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Consider the following reaction,
Q. 
The correct deduction(s) regarding mechanism of the above reaction is/are
  • a)
    Reaction involves nucleophilic addition at carbonyl carbon
  • b)
    Ketones are more reactive than aldehyde
  • c)
    If carbonyl carbon turns chiral, racemic mixture of products is formed provided no other chiral carbon is present
  • d)
    If the intermediate aluminium salt is hydrolysed with DCI-D2O deuterated alcohol (R—OD) is formed
Correct answer is option 'A,C,D'. Can you explain this answer?
Verified Answer
Consider the following reaction,Q.The correct deduction(s) regarding m...
H- (hydride) ion undergoes nu cle ophilic ad dition at sp2 carbon of carbonyls. Aldehydes are more reactive than ketones due to less steric hindrance in former case. Since, nucleophilic attack of hydride ion occur at planar carbonyl carbon, there is equal probability of attack from both side of plane giving racemic mixture if chiral carbon is generated.
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Consider the following reaction,Q.The correct deduction(s) regarding mechanism of the above reaction is/area)Reaction involves nucleophilic addition at carbonyl carbonb)Ketones are more reactive than aldehydec)If carbonyl carbon turns chiral, racemic mixture of products is formed provided no other chiral carbon is presentd)If the intermediate aluminium salt is hydrolysed with DCI-D2Odeuterated alcohol (R—OD) is formedCorrect answer is option 'A,C,D'. Can you explain this answer?
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Consider the following reaction,Q.The correct deduction(s) regarding mechanism of the above reaction is/area)Reaction involves nucleophilic addition at carbonyl carbonb)Ketones are more reactive than aldehydec)If carbonyl carbon turns chiral, racemic mixture of products is formed provided no other chiral carbon is presentd)If the intermediate aluminium salt is hydrolysed with DCI-D2Odeuterated alcohol (R—OD) is formedCorrect answer is option 'A,C,D'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Consider the following reaction,Q.The correct deduction(s) regarding mechanism of the above reaction is/area)Reaction involves nucleophilic addition at carbonyl carbonb)Ketones are more reactive than aldehydec)If carbonyl carbon turns chiral, racemic mixture of products is formed provided no other chiral carbon is presentd)If the intermediate aluminium salt is hydrolysed with DCI-D2Odeuterated alcohol (R—OD) is formedCorrect answer is option 'A,C,D'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Consider the following reaction,Q.The correct deduction(s) regarding mechanism of the above reaction is/area)Reaction involves nucleophilic addition at carbonyl carbonb)Ketones are more reactive than aldehydec)If carbonyl carbon turns chiral, racemic mixture of products is formed provided no other chiral carbon is presentd)If the intermediate aluminium salt is hydrolysed with DCI-D2Odeuterated alcohol (R—OD) is formedCorrect answer is option 'A,C,D'. Can you explain this answer?.
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