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Which of the statement given below concerning 3-methyl-2-butanol is/are correct ?
  • a)
    Treatment with cold, concentrated H2SO4 convert it into achiral 2-methyl-2-butanol
  • b)
    Treatment with NaOH solution convert it into 2-methyl-2-butanol
  • c)
    Treatment of its pure enantiomer with PCI5 gives mainly a pure enantiomer of chloroalkane
  • d)
    It changes the orange colour of acidic K2Cr2O7 solution to blue green
Correct answer is option 'A,C,D'. Can you explain this answer?
Verified Answer
Which of the statement given below concerning 3-methyl-2-butanol is/ar...

(c) PCI5 brings about SN2 reaction, chloro alkane with inverted configuration would be produced.
(d) 3-methyl-2-butanol is a secondary alcohol, will be oxidised to ketone with acidic dichromate solution.
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Which of the statement given below concerning 3-methyl-2-butanol is/ar...

Explanation:

Treatment with cold, concentrated H2SO4
- Treatment with cold, concentrated H2SO4 converts 3-methyl-2-butanol into achiral 2-methyl-2-butanol.
- This reaction involves the dehydration of the alcohol to form an alkene, resulting in the loss of chirality.

Treatment with NaOH solution
- Treatment with NaOH solution does not convert 3-methyl-2-butanol into 2-methyl-2-butanol. This statement is incorrect.

Treatment of its pure enantiomer with PCl5
- Treatment of the pure enantiomer of 3-methyl-2-butanol with PCl5 gives mainly a pure enantiomer of chloroalkane.
- This reaction involves the replacement of the hydroxyl group with a chlorine atom, maintaining the chirality of the molecule.

Change in the color of acidic K2Cr2O7 solution
- 3-methyl-2-butanol changes the orange color of acidic K2Cr2O7 solution to blue-green.
- This indicates the oxidation of the alcohol to a ketone, causing the color change in the chromium solution.
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Which of the statement given below concerning 3-methyl-2-butanol is/are correct ?a)Treatment with cold, concentrated H2SO4convert it into achiral 2-methyl-2-butanolb)Treatment with NaOH solution convert it into 2-methyl-2-butanolc)Treatment of its pure enantiomer with PCI5 gives mainly a pure enantiomer of chloroalkaned)It changes the orange colour of acidic K2Cr2O7 solution to blue greenCorrect answer is option 'A,C,D'. Can you explain this answer?
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Which of the statement given below concerning 3-methyl-2-butanol is/are correct ?a)Treatment with cold, concentrated H2SO4convert it into achiral 2-methyl-2-butanolb)Treatment with NaOH solution convert it into 2-methyl-2-butanolc)Treatment of its pure enantiomer with PCI5 gives mainly a pure enantiomer of chloroalkaned)It changes the orange colour of acidic K2Cr2O7 solution to blue greenCorrect answer is option 'A,C,D'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Which of the statement given below concerning 3-methyl-2-butanol is/are correct ?a)Treatment with cold, concentrated H2SO4convert it into achiral 2-methyl-2-butanolb)Treatment with NaOH solution convert it into 2-methyl-2-butanolc)Treatment of its pure enantiomer with PCI5 gives mainly a pure enantiomer of chloroalkaned)It changes the orange colour of acidic K2Cr2O7 solution to blue greenCorrect answer is option 'A,C,D'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the statement given below concerning 3-methyl-2-butanol is/are correct ?a)Treatment with cold, concentrated H2SO4convert it into achiral 2-methyl-2-butanolb)Treatment with NaOH solution convert it into 2-methyl-2-butanolc)Treatment of its pure enantiomer with PCI5 gives mainly a pure enantiomer of chloroalkaned)It changes the orange colour of acidic K2Cr2O7 solution to blue greenCorrect answer is option 'A,C,D'. Can you explain this answer?.
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