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A nitrogen containg organic compound on heating with chloroform and alcoholic koh evolved unpleasant smell vapour then the compund could be?
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A nitrogen containg organic compound on heating with chloroform and al...
Identification of Nitrogen-Containing Organic Compound


Reaction

The given nitrogen-containing organic compound is heated with chloroform and alcoholic KOH. If the reaction produces an unpleasant smell vapor, then it indicates the presence of an amine functional group in the compound.

Explanation

When the nitrogen-containing organic compound is heated with chloroform and alcoholic KOH, the amine functional group undergoes a reaction known as the Hofmann's degradation reaction. This reaction involves the conversion of the amine functional group into an isocyanate intermediate, which then reacts with the chloroform and alcoholic KOH to produce an unpleasant smell vapor.

Examples

Some examples of nitrogen-containing organic compounds that can undergo Hofmann's degradation reaction include:


  • Primary amines

  • Secondary amines

  • Tertiary amines

  • Amides



Conclusion

In conclusion, the given nitrogen-containing organic compound can be identified by heating it with chloroform and alcoholic KOH and observing the production of an unpleasant smell vapor. This reaction indicates the presence of an amine functional group in the compound.
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A nitrogen containg organic compound on heating with chloroform and alcoholic koh evolved unpleasant smell vapour then the compund could be?
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