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Only One Option Correct Type
Direction (Q. Nos. 1-8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.
Q. 
The incorrect statement concerning E1 reaction is
  • a)
    polar protic solvent increases reactivit
  • b)
    lewis acid catalyses reaction
  • c)
    reaction proceeds via carbocation intermediates
  • d)
    reaction proceeds via a single transition state
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
Only One Option Correct TypeDirection (Q. Nos. 1-8) This section conta...
E1 Reactions involve carbocation intermediates which has characteristics of rearrangement into more stable carbocation, hence involves more than one transition states (usually).
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Only One Option Correct TypeDirection (Q. Nos. 1-8) This section conta...
E1 reaction:
The E1 reaction is a type of elimination reaction in organic chemistry. It involves the removal of a leaving group from a substrate to form a double bond. The E1 reaction proceeds in two steps: the formation of a carbocation intermediate and the elimination of a leaving group.

Incorrect statement:
The incorrect statement concerning the E1 reaction is option (d) - "reaction proceeds via a single transition state."

Explanation:
The E1 reaction proceeds via a two-step mechanism, involving the formation of a carbocation intermediate. In the first step, the leaving group departs from the substrate, forming a carbocation. In the second step, a base or nucleophile removes a proton from an adjacent carbon, resulting in the formation of a double bond and the regeneration of the base or nucleophile. This reaction mechanism involves the formation of a carbocation intermediate and is known as a two-step process.

Reasons why option (d) is incorrect:
1. The E1 reaction proceeds via a two-step mechanism and not a single transition state. A transition state refers to a high-energy, intermediate state that occurs during a reaction. In the case of the E1 reaction, a carbocation intermediate is formed before the elimination step occurs.
2. The formation of a carbocation intermediate indicates that there is an energy barrier between the reactant and product. This energy barrier corresponds to the transition state between the two steps of the E1 reaction.
3. The E1 reaction is characterized by a first-order kinetics, which is consistent with a two-step mechanism involving the formation of a carbocation intermediate. If the reaction proceeded via a single transition state, the kinetics would be different.

Correct statement:
The correct statement concerning the E1 reaction is option (a) - "polar protic solvent increases reactivity." A polar protic solvent can stabilize the carbocation intermediate and increase the reactivity of the E1 reaction.

In summary, the E1 reaction proceeds via a two-step mechanism involving the formation of a carbocation intermediate. It does not proceed via a single transition state. The incorrect statement concerning the E1 reaction is option (d).
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Read the passage given below and answer the following questions:Nucleophilic substitution reaction of haloalkane can be conducted according to both SN1 and SN2 mechanisms. However, which mechanism it is based on is related to such factors as the structure of haloalkane, and properties of leaving group, nucleophilic reagent and solvent. Influences of halogen: No matter which mechanism the nucleophilic substitution reaction is based on, the leaving group always leave the central carbon atom with electron pair. This is just the opposite of the situation that nucleophilic reagent attacks the central carbon atom with electron pair. Therefore, the weaker the alkalinity of leaving group is , the more stable the anion formed is and it will be more easier for the leaving group to leave the central carbon atom; that is to say, the reactant is more easier to be substituted. The alkalinity order of halogen ion is I− < Br− < Cl− < F− and the order of their leaving tendency should be I− > Br− > Cl− > F−. Therefore, in four halides with the same alkyl and different halogens, the order of substitution reaction rate is RI > RBr > RCl > RF. In addition, if the leaving group is very easy to leave, many carbocation intermediates are generated in the reaction and the reaction is based on SN1 mechanism. If the leaving group is not easy to leave, the reaction is based on SN2 mechanism. Influences of solvent polarity: In SN1 reaction, the polarity of the system increases from the reactant to the transition state, because polar solvent has a greater stabilizing effect on the transition state than the reactant, thereby reduce activation energy and accelerate the reaction. In SN2 reaction, the polarity of the system generally does not change from the reactant to the transition state and only charge dispersion occurs. At this time, polar solvent has a great stabilizing effect on Nu than the transition state, thereby increasing activation energy and slow down the reaction rate. For example, the decomposition rate (SN1) of tertiary chlorobutane in 25° water (dielectric constant 79) is 300000 times faster than in ethanol (dielectric constant 24). The reaction rate (SN2) of 2-bromopropane and NaOH in ethanol containing 40% water is twice slower than in absolute ethanol. In a word, the level of solvent polarity has influence on both SN1 and SN2 reactions, but with different results. Generally speaking, weak polar solvent is favorable for SN2 reaction, while strong polar solvent is favorable for SN1 reaction, because only under the action of polar solvent can halogenated hydrocarbon dissociate into carbocation and halogen ion and solvents with a strong polarity is favorable for solvation of carbocation, increasing its stability. Generally speaking, the substitution reaction of tertiary haloalkane is based on SN1 mechanism in solvents with a strong polarity (for example, ethanol containing water).Q. Polar solvents make the reaction faster as they

Only One Option Correct TypeDirection (Q. Nos. 1-8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.Q.The incorrect statement concerning E1 reaction isa)polar protic solvent increases reactivitb)lewis acid catalyses reactionc)reaction proceeds via carbocation intermediatesd)reaction proceeds via a single transition stateCorrect answer is option 'D'. Can you explain this answer?
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Only One Option Correct TypeDirection (Q. Nos. 1-8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.Q.The incorrect statement concerning E1 reaction isa)polar protic solvent increases reactivitb)lewis acid catalyses reactionc)reaction proceeds via carbocation intermediatesd)reaction proceeds via a single transition stateCorrect answer is option 'D'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Only One Option Correct TypeDirection (Q. Nos. 1-8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.Q.The incorrect statement concerning E1 reaction isa)polar protic solvent increases reactivitb)lewis acid catalyses reactionc)reaction proceeds via carbocation intermediatesd)reaction proceeds via a single transition stateCorrect answer is option 'D'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Only One Option Correct TypeDirection (Q. Nos. 1-8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.Q.The incorrect statement concerning E1 reaction isa)polar protic solvent increases reactivitb)lewis acid catalyses reactionc)reaction proceeds via carbocation intermediatesd)reaction proceeds via a single transition stateCorrect answer is option 'D'. Can you explain this answer?.
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