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The IUPAC name of the coordination compound K3[Fe(CN)6] is
  • a)
    Tripotassium hexacyanoiron (II)
  • b)
    Potassium hexacyanoiron (II)
  • c)
    Potassium hexacyanoferrate (III)
  • d)
    Potassium hexacyanoferrate (II)
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
The IUPAC name of the coordination compound K3[Fe(CN)6] isa)Tripotassi...
K3[Fe(CN)6] is potassium hexacyano ferrate (III).
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The IUPAC name of the coordination compound K3[Fe(CN)6] isa)Tripotassi...
IUPAC name of the coordination compound K3[Fe(CN)6]

The coordination compound K3[Fe(CN)6] can be named using the IUPAC nomenclature system which is based on the rules established by the International Union of Pure and Applied Chemistry. The correct answer is option 'C', which is potassium hexacyanoferrate (III).

Explanation:

- Identification of the central metal atom/ion: The central metal ion in this coordination compound is Fe which is iron.
- Identification of the ligands: The ligands in this coordination compound are CN which is cyanide ion.
- Determination of the oxidation state of the central metal ion: The oxidation state of Fe can be calculated as follows:
Total charge on ligands = -6 (since there are six CN ligands, each with a charge of -1)
Total charge on the complex ion = -3 (since the compound has a charge of +3 due to the three potassium ions)
Therefore, the oxidation state of Fe = +3
- Writing the name: To name the compound, the ligands are named first, followed by the name of the central metal atom/ion. The oxidation state of the central metal ion is indicated in parentheses using Roman numerals.
- Therefore, the correct IUPAC name of the coordination compound K3[Fe(CN)6] is potassium hexacyanoferrate (III).
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The IUPAC name of the coordination compound K3[Fe(CN)6] isa)Tripotassium hexacyanoiron (II)b)Potassium hexacyanoiron (II)c)Potassium hexacyanoferrate (III)d)Potassium hexacyanoferrate (II)Correct answer is option 'C'. Can you explain this answer?
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