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Pick out the compound which reacts fastest in the presence of AgNO3.
  • a)
    (CH3)3CCI
  • b)
    (CH3)2CHCH2CI
  • c)
    (CH3)2CHCI
  • d)
    CH3CH2CI
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Pick out the compound which reacts fastest in the presence of AgNO3.a)...
Tertiary halide would react at fastest rate with AgNO3 as reaction will proceed by SN1 mechanism.
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Pick out the compound which reacts fastest in the presence of AgNO3.a)...
Reaction of compounds with AgNO3
- AgNO3 is a silver salt that is commonly used as a reagent to test for the presence of halides in organic compounds.
- When AgNO3 is added to a halide-containing organic compound, a white precipitate of AgX is formed, where X is the halide (Cl, Br, or I).
- The rate of this reaction depends on the reactivity of the halide, with more reactive halides forming precipitates faster.

Comparison of compounds
- The three compounds given are (CH3)3CCI, (CH3)2CHCH2CI, and (CH3)2CHCI.
- All three compounds contain a halide (Cl) that can react with AgNO3 to form a precipitate.
- (CH3)3CCI has three methyl groups attached to the carbon with the Cl, making it more bulky and less reactive than the other two compounds.
- (CH3)2CHCI has two methyl groups attached to the carbon with the Cl, and (CH3)2CHCH2CI has one methyl group and a longer chain attached to the carbon with the Cl.
- Therefore, (CH3)2CHCI is expected to be more reactive than (CH3)3CCI, but less reactive than (CH3)2CHCH2CI.

Conclusion
- The correct answer is option A, (CH3)3CCI, which is the least reactive of the three compounds due to its bulkiness.
- This is because the reaction rate of the compounds with AgNO3 depends on the reactivity of the halide, and the more bulky compound is expected to be less reactive.
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Pick out the compound which reacts fastest in the presence of AgNO3.a)...
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