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Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl-, CN- and H2O respectively, are
(2011, Only One Option Correct Type)
  • a)
    octahedral,tetrahedral and square planer
  • b)
    tetrahedral ,square planer and octahedral
  • c)
    square planer,tetrahedral and octahedral
  • d)
    octahedral,square planer and octahedral
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Geometrical shapes of the complexes formed by the reaction of Ni2+ wit...
Ni2+ + 4CN- → [Ni(CN)4]2- 
Here, Ni2+ has d8 configuration with CN- as strong ligand.

d8 configuration in strong ligand field gives dsp2 hybridisation, hence square planar geometry.
Ni2+ + 4Cl- → [NiCI4]2-
Here, Ni2+ has d8 configuration with Cl- as weak ligand.



d8 configuration in weak ligand field gives sp3 hydridisation, hence tetrahedral geometry.
Ni2+ with H2O forms [Ni(H2O)6]2+ complex and H2O is a weak ligand.


Therefore, [Ni(H2O)6]2+ has octahedral geometry.
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Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl-, CN-and H2Orespectively, are(2011, Only One Option Correct Type)a)octahedral,tetrahedral and square planerb)tetrahedral ,square planer and octahedralc)square planer,tetrahedral and octahedrald)octahedral,square planer and octahedralCorrect answer is option 'B'. Can you explain this answer?
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Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl-, CN-and H2Orespectively, are(2011, Only One Option Correct Type)a)octahedral,tetrahedral and square planerb)tetrahedral ,square planer and octahedralc)square planer,tetrahedral and octahedrald)octahedral,square planer and octahedralCorrect answer is option 'B'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl-, CN-and H2Orespectively, are(2011, Only One Option Correct Type)a)octahedral,tetrahedral and square planerb)tetrahedral ,square planer and octahedralc)square planer,tetrahedral and octahedrald)octahedral,square planer and octahedralCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl-, CN-and H2Orespectively, are(2011, Only One Option Correct Type)a)octahedral,tetrahedral and square planerb)tetrahedral ,square planer and octahedralc)square planer,tetrahedral and octahedrald)octahedral,square planer and octahedralCorrect answer is option 'B'. Can you explain this answer?.
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