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1.2 g of a salt with its empirical formula KxHy(C2O4)z was dissolved in 50 mL of water and its 10 mL portion required 11 mL of a 0.1 M HCl solution to reach the equivalence point. In a separate titration, 15 mL of the stock solution required 20 mL 0.2475 M KOH to reach the equivalence point. Identify the correct option.
  • a)
    y = 3x
  • b)
    y = 2x
  • c)
    y = 4x
  • d)
    y = 5x
Correct answer is option 'A'. Can you explain this answer?
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1.2 g of a salt with its empirical formula KxHy(C2O4)zwas dissolved in...




∴ y = 3x.
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1.2 g of a salt with its empirical formula KxHy(C2O4)zwas dissolved in...
Given:
- 1.2 g of a salt with empirical formula KxHy(C2O4)z was dissolved in 50 mL of water
- 10 mL of the solution required 11 mL of 0.1 M HCl to reach equivalence point
- 15 mL of the solution required 20 mL of 0.2475 M KOH to reach equivalence point

To find: Empirical formula of the salt

Solution:
1. Calculation of moles of HCl used in titration
Molarity of HCl solution = 0.1 M
Volume of HCl solution used = 11 mL = 0.011 L
Moles of HCl = Molarity x Volume = 0.1 x 0.011 = 0.0011 moles

2. Calculation of moles of KOH used in titration
Molarity of KOH solution = 0.2475 M
Volume of KOH solution used = 20 mL = 0.02 L
Moles of KOH = Molarity x Volume = 0.2475 x 0.02 = 0.00495 moles

3. Calculation of moles of salt used in titration
Moles of salt used in HCl titration = Moles of HCl used (from step 1)
= 0.0011 moles
Moles of salt used in KOH titration = Moles of KOH used (from step 2)
= 0.00495 moles

4. Calculation of empirical formula of the salt
Empirical formula mass of salt = (39.1x + 1.008y + 90.04z) g/mol (using atomic masses)
Moles of salt used in titrations = 0.0011 + 0.00495 = 0.00605 moles
Mass of salt used in solution = 1.2 g
Moles of salt in solution = mass/molar mass = 1.2/[(39.1x + 1.008y + 90.04z) g/mol]
Equating the two values of moles, we get:
0.00605 = 1.2/[(39.1x + 1.008y + 90.04z) g/mol]
Simplifying, we get:
39.1x + 1.008y + 90.04z = 197.351
Dividing by 1.2, we get:
32.583x + 0.84y + 75.033z = 164.459
Substituting the possible values of x, we get:
For x=1, y=3, z=2: LHS = 32.583 + 2.524 + 150.066 = 185.173
For x=2, y=3, z=1: LHS = 65.166 + 2.524 + 90.04 = 157.73
For x=3, y=2, z=2: LHS = 97.749 + 2.016 + 150.066 = 249.831
For x=4, y=1, z=3: LHS = 130.332 + 1.008 + 270.12 = 401
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1.2 g of a salt with its empirical formula KxHy(C2O4)zwas dissolved in 50 mL of water and its 10 mL portion required 11 mL of a 0.1 M HCl solution to reach the equivalence point. In a separate titration, 15 mL of the stock solution required 20 mL 0.2475 M KOH to reach the equivalence point. Identify the correct option.a)y = 3xb)y = 2xc)y = 4xd)y = 5xCorrect answer is option 'A'. Can you explain this answer?
Question Description
1.2 g of a salt with its empirical formula KxHy(C2O4)zwas dissolved in 50 mL of water and its 10 mL portion required 11 mL of a 0.1 M HCl solution to reach the equivalence point. In a separate titration, 15 mL of the stock solution required 20 mL 0.2475 M KOH to reach the equivalence point. Identify the correct option.a)y = 3xb)y = 2xc)y = 4xd)y = 5xCorrect answer is option 'A'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about 1.2 g of a salt with its empirical formula KxHy(C2O4)zwas dissolved in 50 mL of water and its 10 mL portion required 11 mL of a 0.1 M HCl solution to reach the equivalence point. In a separate titration, 15 mL of the stock solution required 20 mL 0.2475 M KOH to reach the equivalence point. Identify the correct option.a)y = 3xb)y = 2xc)y = 4xd)y = 5xCorrect answer is option 'A'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for 1.2 g of a salt with its empirical formula KxHy(C2O4)zwas dissolved in 50 mL of water and its 10 mL portion required 11 mL of a 0.1 M HCl solution to reach the equivalence point. In a separate titration, 15 mL of the stock solution required 20 mL 0.2475 M KOH to reach the equivalence point. Identify the correct option.a)y = 3xb)y = 2xc)y = 4xd)y = 5xCorrect answer is option 'A'. Can you explain this answer?.
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