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Passage III
is believed to proceed through the following three step mechanism:


Q.
Identify the false statement.
  • a)
    The molecularity of each step is 2
  • b)
    The limiting step is II
  • c)
    HOCI is only the reaction intermediate
  • d)
    The reaction is a complex reaction
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
Passage IIIis believed to proceed through the following three step mec...
Molecularity of each step is two thus, true.
Thus, (a) is correct.
The limiting step of a complex reaction is always the slowest, thus (b) is correct.
It involves more than one elementary step, thus, it is a complex reaction. Thus, (d) is also correct.
HOCl appears in step I and disappears in step II, Thus it is an intermediate.
HOI appears in step II and disappears in step III. Thus, HOI is also an intermediate.
Thus, (c) is incorrect.
Slow step il is the rate-determining step.


Note H2O as reactant is not taken in equilibrium and rate expression.
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