Chemistry Exam > Chemistry Questions > In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][T...
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In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anions respectively are
- a)Both square pyramidal
- b)square pyramidal and trigonal bipyramidal
- c)Trigonal bipyramidal and square pyramidal
- d)both trigonal bipyramidal
Correct answer is option 'C'. Can you explain this answer?
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In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anio...
The structures of anions in two different salts, [Et4N]2[InCl5] and [NH3(CH2)5NH3][TiCl5].
For [Et4N]2[InCl5], the anion is [InCl5]2-. Indium (In) typically forms a trigonal bipyramidal structure with five chloride ions because it can accommodate five ligands around it.
For [NH3(CH2)5NH3][TiCl5], the anion is [TiCl5]2-. Titanium (Ti) in the +4 oxidation state usually forms a square pyramidal structure with five ligands due to its d^0 configuration.
Therefore, the correct answer is:
Option A: Trigonal bipyramidal and square pyramidal.
Most Upvoted Answer
In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anio...
Structure of [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5]
Trigonal Bipyramidal Structure of [Et4N]2[InCI5]
- The anion [InCI5] has a trigonal bipyramidal structure.
- It consists of five chlorine atoms and an indium atom in the center.
- The chlorine atoms are arranged in a trigonal plane, and the other two atoms form axial positions.
- The trigonal plane is formed by three equatorial lone pairs of electrons and two axial chlorine atoms.
- The shape of the anion is trigonal bipyramidal because it has one central atom and five surrounding atoms, which are arranged in a trigonal plane and two axial positions, respectively.
Square Pyramidal Structure of [NH3(CH2)5(NH3)][TiCI5]
- The anion [TiCI5] has a square pyramidal structure.
- It consists of five chlorine atoms and a titanium atom in the center.
- The chlorine atoms are arranged in a square plane, and the other atom forms an axial position.
- The square plane is formed by four equatorial chlorine atoms, and the axial position is occupied by the fifth chlorine atom.
- The shape of the anion is square pyramidal because it has one central atom and five surrounding atoms, which are arranged in a square plane and one axial position, respectively.
Both Anions have Square Pyramidal Structure
- The correct answer is option 'C' because both anions have a square pyramidal structure.
- The anion [Et4N]2[InCI5] has a trigonal bipyramidal structure; however, it is a cation, not an anion.
- The anion [NH3(CH2)5(NH3)][TiCI5] has a square pyramidal structure, as discussed above.
- Therefore, the anions in the given compounds have different structures, and option 'C' is the correct answer.
Trigonal Bipyramidal Structure of [Et4N]2[InCI5]
- The anion [InCI5] has a trigonal bipyramidal structure.
- It consists of five chlorine atoms and an indium atom in the center.
- The chlorine atoms are arranged in a trigonal plane, and the other two atoms form axial positions.
- The trigonal plane is formed by three equatorial lone pairs of electrons and two axial chlorine atoms.
- The shape of the anion is trigonal bipyramidal because it has one central atom and five surrounding atoms, which are arranged in a trigonal plane and two axial positions, respectively.
Square Pyramidal Structure of [NH3(CH2)5(NH3)][TiCI5]
- The anion [TiCI5] has a square pyramidal structure.
- It consists of five chlorine atoms and a titanium atom in the center.
- The chlorine atoms are arranged in a square plane, and the other atom forms an axial position.
- The square plane is formed by four equatorial chlorine atoms, and the axial position is occupied by the fifth chlorine atom.
- The shape of the anion is square pyramidal because it has one central atom and five surrounding atoms, which are arranged in a square plane and one axial position, respectively.
Both Anions have Square Pyramidal Structure
- The correct answer is option 'C' because both anions have a square pyramidal structure.
- The anion [Et4N]2[InCI5] has a trigonal bipyramidal structure; however, it is a cation, not an anion.
- The anion [NH3(CH2)5(NH3)][TiCI5] has a square pyramidal structure, as discussed above.
- Therefore, the anions in the given compounds have different structures, and option 'C' is the correct answer.
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In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anions respectively area)Both square pyramidalb)square pyramidal and trigonal bipyramidalc)Trigonal bipyramidal and square pyramidald)both trigonal bipyramidalCorrect answer is option 'C'. Can you explain this answer?
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In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anions respectively area)Both square pyramidalb)square pyramidal and trigonal bipyramidalc)Trigonal bipyramidal and square pyramidald)both trigonal bipyramidalCorrect answer is option 'C'. Can you explain this answer? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anions respectively area)Both square pyramidalb)square pyramidal and trigonal bipyramidalc)Trigonal bipyramidal and square pyramidald)both trigonal bipyramidalCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anions respectively area)Both square pyramidalb)square pyramidal and trigonal bipyramidalc)Trigonal bipyramidal and square pyramidald)both trigonal bipyramidalCorrect answer is option 'C'. Can you explain this answer?.
In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anions respectively area)Both square pyramidalb)square pyramidal and trigonal bipyramidalc)Trigonal bipyramidal and square pyramidald)both trigonal bipyramidalCorrect answer is option 'C'. Can you explain this answer? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anions respectively area)Both square pyramidalb)square pyramidal and trigonal bipyramidalc)Trigonal bipyramidal and square pyramidald)both trigonal bipyramidalCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for In salt [Et4N]2[InCI5] and [NH3(CH2)5(NH3)][TiCI5], structures of anions respectively area)Both square pyramidalb)square pyramidal and trigonal bipyramidalc)Trigonal bipyramidal and square pyramidald)both trigonal bipyramidalCorrect answer is option 'C'. Can you explain this answer?.
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