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The reaction of toluene with Cl2 in presence of FeCl3 gives predominantly [2007]
  • a)
    m-chlorobenzene
  • b)
    benzoyl chloride
  • c)
    benzyl chloride
  • d)
    o- and p-chlorotoluene.
Correct answer is option 'D'. Can you explain this answer?
Most Upvoted Answer
The reaction of toluene with Cl2 in presence of FeCl3 gives predominan...
The CH3 group in toluene shows both +I and Hyperconjugation effects which activate the Benzene ring. Thus -ve charge density increases (at the o- and p- positions). Now, the above reaction includes halogenation of Benzene which is an example of electrophilic aromatic substitution reaction. FeCl3 acts as a Lewis acid and takes Cl from Cl2 forming FeCl4- and Cl+. The latter being an electrophile attacks the ring at the o- and p- positions to form the respective products.
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The reaction of toluene with Cl2 in presence of FeCl3 gives predominantly [2007]a)m-chlorobenzeneb)benzoyl chloridec)benzyl chlorided)o- and p-chlorotoluene.Correct answer is option 'D'. Can you explain this answer?
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