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The reaction of toluene with Cl2 in presence of FeCl3 gives predominantly [2007]
- a)m-chlorobenzene
- b)benzoyl chloride
- c)benzyl chloride
- d)o- and p-chlorotoluene.
Correct answer is option 'D'. Can you explain this answer?
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The reaction of toluene with Cl2 in presence of FeCl3 gives predominan...
The CH3 group in toluene shows both +I and Hyperconjugation effects which activate the Benzene ring. Thus -ve charge density increases (at the o- and p- positions). Now, the above reaction includes halogenation of Benzene which is an example of electrophilic aromatic substitution reaction. FeCl3 acts as a Lewis acid and takes Cl from Cl2 forming FeCl4- and Cl+. The latter being an electrophile attacks the ring at the o- and p- positions to form the respective products.
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The reaction of toluene with Cl2 in presence of FeCl3 gives predominantly [2007]a)m-chlorobenzeneb)benzoyl chloridec)benzyl chlorided)o- and p-chlorotoluene.Correct answer is option 'D'. Can you explain this answer?
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