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The synthesis of alkyl fluorides is best accomplished by :        [JEE M 2015]
  • a)
    Finkelstein reaction
  • b)
    Swarts reaction
  • c)
    Free radical fluorination
  • d)
    Sandmeyer's reaction
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
The synthesis of alkyl fluorides is best accomplished by: [JEE M 20...
Correct Option (B) Swarts reaction
Explanation:

Alkyl fluorides can be prepared by action of mercurous fluoride or antimony trifluorides (inorganic fluorides) on corresponding alkyl halide. This reaction is known as Swarts reaction.

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The synthesis of alkyl fluorides is best accomplished by: [JEE M 20...
Swarts Reaction for Synthesis of Alkyl Fluorides
The Swarts reaction is a method for the synthesis of alkyl fluorides. It involves the conversion of alkyl chlorides or bromides to alkyl fluorides by the action of a fluoride source such as HF or metal fluorides. Here's how the Swarts reaction works:

Key Points:
- Alkyl chlorides or bromides are treated with a fluoride source such as HF or metal fluorides.
- The reaction proceeds via a nucleophilic substitution mechanism where the chlorine or bromine atom is replaced by a fluorine atom.
- The use of HF as a fluoride source can lead to side reactions and is not the preferred method.
- Metal fluorides such as AgF or SbF3 are commonly used as they provide better control and higher yields.

Advantages of Swarts Reaction:
- It is a straightforward method for the synthesis of alkyl fluorides.
- Metal fluorides provide better selectivity and yield compared to HF.
- The reaction can be easily scaled up for industrial applications.

Limitations of Swarts Reaction:
- The Swarts reaction can be limited by the availability of suitable starting materials.
- Care must be taken to avoid side reactions and to ensure the desired product is obtained.
In conclusion, the Swarts reaction is a reliable method for the synthesis of alkyl fluorides from alkyl chlorides or bromides. It offers good control over the reaction and can be scaled up for industrial use.
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The synthesis of alkyl fluorides is best accomplished by: [JEE M 2015]a)Finkelstein reactionb)Swarts reactionc)Free radical fluorinationd)Sandmeyer's reactionCorrect answer is option 'B'. Can you explain this answer?
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