An organic compound X is oxidised by using acidifiedK2Cr2O7. The produ...
Yup...it will be propan-2-ol..by oxidation it..it will convert into acetone and it reacts with phenyl hydrazine,it produces acetone phenyl hydrazone and there is no aldehyde grp in acetone. so it doesn't react in silver mirror test means with tollen's reagent..
An organic compound X is oxidised by using acidifiedK2Cr2O7. The produ...
Answer:
Explanation:
To determine the possible structure of compound X, we need to consider the given information about its reactions with acidified K2Cr2O7 and phenyl hydrazine, as well as its non-reactivity in the silver mirror test.
Reaction with Acidified K2Cr2O7:
The oxidation of an organic compound by acidified K2Cr2O7 involves the conversion of the Cr(VI) in K2Cr2O7 to Cr(III). In this process, the organic compound is oxidized while K2Cr2O7 is reduced.
Phenyl Hydrazine Test:
Phenyl hydrazine is commonly used to test for the presence of carbonyl compounds, particularly aldehydes and ketones. It reacts with carbonyl compounds to form hydrazones, which are yellow or orange precipitates.
Silver Mirror Test:
The silver mirror test is used to identify the presence of an aldehyde functional group in an organic compound. It involves the reaction of the compound with Tollens' reagent (ammoniacal silver nitrate), which results in the formation of a silver mirror on the walls of the test tube.
Possible Structures:
Let's consider the given options one by one:
a) CH3CH2OH (Ethanol)
- Ethanol can be oxidized by acidified K2Cr2O7 to form ethanal (CH3CHO).
- Ethanal can react with phenyl hydrazine to form a yellow/orange precipitate.
- Ethanol can also produce a silver mirror when subjected to the silver mirror test.
- Therefore, option a) is not the correct answer.
b) CH3CHO (Ethanal)
- Ethanal can be oxidized by acidified K2Cr2O7 to form ethanoic acid (CH3COOH).
- Ethanal can react with phenyl hydrazine to form a yellow/orange precipitate.
- Ethanal can also produce a silver mirror when subjected to the silver mirror test.
- Therefore, option b) is not the correct answer.
c) (CH3)2CHOH (Isopropyl alcohol)
- Isopropyl alcohol can be oxidized by acidified K2Cr2O7 to form acetone ((CH3)2CO).
- Acetone does not react with phenyl hydrazine and does not form a yellow/orange precipitate.
- Acetone also does not produce a silver mirror when subjected to the silver mirror test.
- Therefore, option c) is the correct answer.
d) None of these
- The correct answer has already been determined to be option c) (CH3)2CHOH.
In conclusion, the possible structure of compound X is (CH3)2CHOH, which is isopropyl alcohol.