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25 ml of a solution containing NaOH and Na2CO3 required (i) 50 ml of 0.2 N HCl using phenolphthalein as an indicator (ii) 72 ml of 0.2 N HCl when titrated using methyl blue as indicator. The ratio of weight of NaOH and Na2CO3 in the solution is a) 0.48 b) 0.44 c) 0.4 d) 0.38?
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25 ml of a solution containing NaOH and Na2CO3 required (i) 50 ml of 0...
Solution:

Given,

Volume of solution = 25 ml

Volume of 0.2 N HCl required with phenolphthalein as an indicator = 50 ml

Volume of 0.2 N HCl required with methyl blue as an indicator = 72 ml

Let us take the weight of NaOH and Na2CO3 as x and y respectively.

Then,

1) N1V1 = N2V2

Where,

N1 = Normality of HCl = 0.2 N

V1 = Volume of HCl = 50 ml

N2 = Normality of the given solution

V2 = Volume of the given solution

We can calculate the normality of the given solution as follows:

25 ml of the given solution contains NaOH and Na2CO3.

Let the concentration of NaOH and Na2CO3 be x and y respectively.

Molecular weight of NaOH = 40

Molecular weight of Na2CO3 = (2 x 23) + 12 + (3 x 16) = 106

So,

x + y = concentration of the given solution

40x/106 + 2y/106 = N2

=> 20x/53 + y/53 = N2

=> 0.377 (x + y) = N2

Using the above value in equation (1),

0.2 x 50 = N2 x 25

N2 = 0.4 N

2) Using methyl blue indicator:

N1V1 = N2V2

Where,

N1 = Normality of HCl = 0.2 N

V1 = Volume of HCl = 72 ml

N2 = Normality of Na2CO3

V2 = Volume of the given solution

Here, NaOH does not react with methyl blue.

So,

N2 = N1 x (V1 - V2)/V2

=> N2 = 0.2 x (72 - 50)/50

=> N2 = 0.064 N

Now, we can write two equations using the weight of NaOH and Na2CO3 and solve them to get the ratio of their weights.

Let us consider the weight of NaOH and Na2CO3 to be x and y respectively.

Weight of NaOH = x g

Weight of Na2CO3 = y g

Molecular weight of NaOH = 40

Molecular weight of Na2CO3 = (2 x 23) + 12 + (3 x 16) = 106

1) Using phenolphthalein indicator:

0.4 x 50 x 1/40 x 1000 = x

=> x = 50 g

2) Using methyl blue indicator:

0.064 x (25/1000) x 106/1000 = y

=> y = 0.17 g

So, the ratio of weight of NaOH and Na2CO3 in the solution is:

x/y = 50/0.17 = 294.12

=> x:y = 294.12:1

=> y/x = 1/294.12

=> y/(x+y) = 1/(294.12+1)

=> y/(x+y) = 0.00338

So,

Community Answer
25 ml of a solution containing NaOH and Na2CO3 required (i) 50 ml of 0...
In case of phonophthalin na2co3 converted to nahco3 & for methyl orange it convert to h2co3
so Valency factor changes
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25 ml of a solution containing NaOH and Na2CO3 required (i) 50 ml of 0.2 N HCl using phenolphthalein as an indicator (ii) 72 ml of 0.2 N HCl when titrated using methyl blue as indicator. The ratio of weight of NaOH and Na2CO3 in the solution is a) 0.48 b) 0.44 c) 0.4 d) 0.38?
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25 ml of a solution containing NaOH and Na2CO3 required (i) 50 ml of 0.2 N HCl using phenolphthalein as an indicator (ii) 72 ml of 0.2 N HCl when titrated using methyl blue as indicator. The ratio of weight of NaOH and Na2CO3 in the solution is a) 0.48 b) 0.44 c) 0.4 d) 0.38? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about 25 ml of a solution containing NaOH and Na2CO3 required (i) 50 ml of 0.2 N HCl using phenolphthalein as an indicator (ii) 72 ml of 0.2 N HCl when titrated using methyl blue as indicator. The ratio of weight of NaOH and Na2CO3 in the solution is a) 0.48 b) 0.44 c) 0.4 d) 0.38? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for 25 ml of a solution containing NaOH and Na2CO3 required (i) 50 ml of 0.2 N HCl using phenolphthalein as an indicator (ii) 72 ml of 0.2 N HCl when titrated using methyl blue as indicator. The ratio of weight of NaOH and Na2CO3 in the solution is a) 0.48 b) 0.44 c) 0.4 d) 0.38?.
Solutions for 25 ml of a solution containing NaOH and Na2CO3 required (i) 50 ml of 0.2 N HCl using phenolphthalein as an indicator (ii) 72 ml of 0.2 N HCl when titrated using methyl blue as indicator. The ratio of weight of NaOH and Na2CO3 in the solution is a) 0.48 b) 0.44 c) 0.4 d) 0.38? in English & in Hindi are available as part of our courses for JEE. Download more important topics, notes, lectures and mock test series for JEE Exam by signing up for free.
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