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The state of an ideal gas is changed from (T1, P1) to (T2, P2) in a constant volume process. To calculate the change in enthalpy (Δh) ail of the following properties/variables are required.

  • a)
    Cv,P1, P2

  • b)
    Cp, T1, T2

  • c)
    Cp, T1, T2, P1, P2

  • d)
    Cv, P1 P2, T1, T2

Correct answer is option 'B'. Can you explain this answer?
Verified Answer
The state of an ideal gas is changed from (T1, P1) to (T2, P2) in a co...
Calculation of Change in Enthalpy (Δh) in Constant Volume Process



- Properties/Variables Required:

- Cp (specific heat at constant pressure)

- Initial temperature (T1)

- Final temperature (T2)



- In a constant volume process, the enthalpy change (Δh) is equal to the heat added to the system. The formula for calculating the change in enthalpy is Δh = Cp * (T2 - T1).



- Cp is the specific heat at constant pressure, which represents the amount of heat required to raise the temperature of one unit mass of a substance by one degree Celsius at constant pressure.



- We need the initial temperature (T1) and final temperature (T2) to calculate the change in enthalpy, as the enthalpy change is directly proportional to the temperature change.



- Therefore, the properties/variables required to calculate the change in enthalpy (Δh) in a constant volume process are Cp, T1, and T2.
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Most Upvoted Answer
The state of an ideal gas is changed from (T1, P1) to (T2, P2) in a co...
ΔH) we can use the formula:

ΔH = Cp * ΔT

Where Cp is the specific heat at constant pressure and ΔT is the change in temperature.

Since the process is constant volume, the work done is zero and therefore ΔU = q, where ΔU is the change in internal energy and q is the heat transferred.

Using the first law of thermodynamics, we have:

ΔU = q - w

Since w = 0, we have:

ΔU = q

Also, since the process is ideal gas at constant volume, we have:

ΔU = Cv * ΔT

Where Cv is the specific heat at constant volume.

Combining the above equations, we get:

Cv * ΔT = Cp * ΔT - ΔH

Rearranging, we get:

ΔH = Cp * ΔT - Cv * ΔT

Substituting the values for Cp and Cv for an ideal gas (Cp = Cv + R), we get:

ΔH = (Cv + R) * ΔT - Cv * ΔT

Simplifying, we get:

ΔH = R * ΔT

Therefore, the change in enthalpy for an ideal gas undergoing a constant volume process is directly proportional to the change in temperature, and is given by the product of the gas constant and the change in temperature.
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