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Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.
Let a reaction be represented in general terms by the scheme
where k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written as
K = [B] /[A] = K1/K–1                   --(1)
where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given by
d[A]t/dt= - K1[A]t + k-1[B]t
If, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,
[Bat = [A]0 - [A]t, whence
d[A]t/dt = –K1[A]t + k-1([A]O - [A]t)
or
d[A]t/dt = – (K1 + k-1
At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?
  • a)
    t = 0  only
  • b)
    t≥ tequilibriumonly
  • c)
    t = 10 only
  • d)
    at all time
Correct answer is option 'D'. Can you explain this answer?
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Not all chemical reactions proceed to a stage at which the concentrati...
Comparing the given equation with equation (i),
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Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer?
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Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer?.
Solutions for Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer? in English & in Hindi are available as part of our courses for JEE. Download more important topics, notes, lectures and mock test series for JEE Exam by signing up for free.
Here you can find the meaning of Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer?, a detailed solution for Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer? has been provided alongside types of Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Not all chemical reactions proceed to a stage at which the concentrations of the reactants become vanishingly small. Here we consider the kinetics of such reactions.Let a reaction be represented in general terms by the schemewhere k., and k_., represent the rate constants for the forwards and reverse reactions, respectively. The equilibrium constant for this reaction may be written asK = [B] /[A] = K1/K1 --(1)where the subscript 00 refers to a time t, sufficiently long to establish equilibrium at the given temperature. The initial concentration of species A is [A]O, and that of B is [B]O . After a time t, let the concentration of species A be [A/t and that of B be [Bat. The total rate of change of [At is given byd[A]t/dt= - K1[A]t + k-1[B]tIf, as is usual, [B]O is initially zero, it follows from a mass balance that at any time t,[Bat = [A]0 - [A]t, whenced[A]t/dt = K1[A]t + k-1([A]O - [A]t)ord[A]t/dt = (K1 + k-1)At what time is the rate of change of concentration of A equal to rate of change of concentration of C in magnitude ?a)t = 0 onlyb)t tequilibriumonlyc)t = 10 onlyd)at all timeCorrect answer is option 'D'. Can you explain this answer? tests, examples and also practice JEE tests.
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