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The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be increased from 300 K so that rate doubles if activation energy of the reaction B is twice to that of reaction A.
  • a)
    9.84 K
  • b)
    4.92 K
  • c)
    2.45 K
  • d)
    19.67 K
Correct answer is option 'B'. Can you explain this answer?
Most Upvoted Answer
The rate of a reaction A doubles on increasing the temperature from 30...
Given:
- The rate of reaction A doubles on increasing the temperature from 300 K to 310 K.
- The activation energy of reaction B is twice that of reaction A.

To Find:
- By how much should the temperature of reaction B be increased from 300 K so that the rate doubles.

Explanation:
Step 1: Understanding the Effect of Temperature on Reaction Rate
- The rate of a reaction generally increases with an increase in temperature.
- This is because an increase in temperature provides more energy to the reactant molecules, which leads to more frequent and energetic collisions, and hence a higher rate of reaction.

Step 2: Effect of Temperature on Rate Constant
- The rate of a reaction can be expressed using the Arrhenius equation:
k = Ae^(-Ea/RT)
where k is the rate constant, A is the pre-exponential factor, Ea is the activation energy, R is the gas constant, and T is the temperature in Kelvin.
- As temperature increases, the value of RT in the denominator decreases, leading to an increase in the rate constant and hence the rate of reaction.

Step 3: Relationship between Rate and Temperature
- The rate of a reaction is directly proportional to the rate constant:
rate = k[A]^m[B]^n
- If the rate constant doubles, the rate of reaction also doubles.

Step 4: Solution
- In this question, the rate of reaction A doubles on increasing the temperature from 300 K to 310 K.
- Let's assume that the rate constant of reaction A at 300 K is k1 and the rate constant at 310 K is k2.
- Since the rate doubles, we can write:
k2 = 2k1
- Now, let's consider reaction B. The activation energy of reaction B is twice that of reaction A.
- This means that the value of Ea for reaction B is 2 times the value of Ea for reaction A.
- We can use the Arrhenius equation to write the relationship between the rate constants of reaction A and reaction B:
k2 = Ae^(-Ea2/RT)
k1 = Ae^(-Ea1/RT)
- Dividing these two equations, we get:
k2/k1 = e^((Ea1-Ea2)/RT)
- Since k2 = 2k1, we can substitute this value:
2 = e^((Ea1-Ea2)/RT)
- Taking natural logarithm on both sides:
ln(2) = (Ea1-Ea2)/RT
- Rearranging the equation and substituting the given values:
Ea1 - Ea2 = ln(2) * RT
Ea1 - 2Ea1 = ln(2) * RT
Ea1 = -ln(2) * RT
- The temperature of reaction B should be increased by the same amount as the given increase in temperature for reaction A.
- Therefore, the temperature of reaction B should be increased by 10 K.
- Hence, the correct answer is option B) 4.92 K.
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The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be increased from 300 K so that rate doubles if activation energy of the reaction B is twice to that of reaction A.a)9.84 Kb)4.92 Kc)2.45 Kd)19.67 KCorrect answer is option 'B'. Can you explain this answer?
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The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be increased from 300 K so that rate doubles if activation energy of the reaction B is twice to that of reaction A.a)9.84 Kb)4.92 Kc)2.45 Kd)19.67 KCorrect answer is option 'B'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be increased from 300 K so that rate doubles if activation energy of the reaction B is twice to that of reaction A.a)9.84 Kb)4.92 Kc)2.45 Kd)19.67 KCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be increased from 300 K so that rate doubles if activation energy of the reaction B is twice to that of reaction A.a)9.84 Kb)4.92 Kc)2.45 Kd)19.67 KCorrect answer is option 'B'. Can you explain this answer?.
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