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In a reversible reaction, two substances are in equilibrium. If the concentration of each one is reduced to half, the equilibrium constant will be
  • a)
    reduced to half of its original value
  • b)
    doubled
  • c)
    same
  • d)
    reduced to one fourth its original value
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
In a reversible reaction, two substances are in equilibrium. If the co...
Actually, here remember the value of eqm constants,Kp and Kc is always constant and changes only with temperature.
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In a reversible reaction, two substances are in equilibrium. If the co...
Explanation:


When a reversible reaction is at equilibrium, the concentrations of the reactants and products remain constant. The equilibrium constant (K) is a numerical value that represents the ratio of the concentrations of the products to the concentrations of the reactants at equilibrium.

In this case, let's consider a reversible reaction represented as:

A + B ⇌ C + D

Where A and B are reactants and C and D are products.

Now, if the concentration of each substance is reduced to half, we can denote the new concentrations as:

[A] = [A]₀/2
[B] = [B]₀/2
[C] = [C]₀/2
[D] = [D]₀/2

The equilibrium constant (K) is defined as:

K = ([C] * [D]) / ([A] * [B])

Substituting the new concentrations into the equilibrium constant expression, we get:

K' = ([C]₀/2 * [D]₀/2) / ([A]₀/2 * [B]₀/2)

Simplifying the expression, we have:

K' = ([C]₀ * [D]₀) / ([A]₀ * [B]₀) * (1/2 * 1/2)

K' = K * (1/4)

Therefore, the equilibrium constant (K') is reduced to one-fourth (1/4) of its original value (K). Hence, the correct answer is option 'D', i.e., "reduced to one-fourth its original value".

It's important to note that the equilibrium constant depends only on the stoichiometry of the reaction and the temperature, but not on the initial concentrations of the reactants and products. Therefore, reducing the concentration of each substance to half does not change the equilibrium constant value.
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In a reversible reaction, two substances are in equilibrium. If the concentration of each one is reduced to half, the equilibrium constant will bea)reduced to half of its original valueb)doubledc)samed)reduced to one fourth its original valueCorrect answer is option 'C'. Can you explain this answer?
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