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Among the following, the maximum covalent character is shown by the compound
(AIEEE 2011)
  • a)
     FeCI2
  • b)
    SnCI2
  • c)
    AlCl3
  • d)
    MgCI2
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
Among the following, the maximum covalent character is shown by the co...
Covalent character is favoured by Fajans ’ rule.
(i) Larger the charge on the ions,
(ii) Smaller the size of cations,
(iii) Larger the size of anions,
(iv) Cation with 18-electrons structure (e.g.Cu+),
then larger the polarising power and the covalent character is favoured.
In all the given compounds , anion is same (Cl-), hence polarising power is decided by size and charge of cation.
Al3+ with maximum charge and smallest size has maximum polarising power hence, AICI3 is maximum covalent.
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Most Upvoted Answer
Among the following, the maximum covalent character is shown by the co...
Covalent character is favoured by Fajans ’ rule.
(i) Larger the charge on the ions,
(ii) Smaller the size of cations,
(iii) Larger the size of anions,
(iv) Cation with 18-electrons structure (e.g.Cu+),
then larger the polarising power and the covalent character is favoured.
In all the given compounds , anion is same (Cl-), hence polarising power is decided by size and charge of cation.
Al3+ with maximum charge and smallest size has maximum polarising power hence, AICI3 is maximum covalent.
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Among the following, the maximum covalent character is shown by the compound(AIEEE2011)a)FeCI2b)SnCI2c)AlCl3d)MgCI2Correct answer is option 'C'. Can you explain this answer?
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