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Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociation where  n is the number of products (ions or molecules) obtained per mole of the reactant & i =  for association.
Where n is number of reactant particles associated to give 1 mole product. 
A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.
Q. The colligative properties observed will be     
  • a)
  • b)
  • c)
  • d)
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Properties, whose values depend only on the concentration of solute pa...
(A) During association 
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A system of greater disorder of molecules is more probable. The disorder of molecules is reflected by the entropy of the system. A liquid vaporizes to form a more disordered gas. When a solulte is present , there is additional contribution to the entropy of the liquid due to increase randomness. As the entropy of solution is higher than that of pure liquid, there is weaker tendency to form the gas.Thus , a solute (non volatil e) lowers the vapour pressure of a liquid, and hence a higher booing point of the solution Similarly, the greater randomness of the solution opposes the tendency to freeze. In consequence, a lower the temperature must be reached for achieving the equilibrium between the solid (frozen solvent) and the solution . Elevation of B.Pt. Tband depression of F.Pt. Tfof a solution are the colligative properties which depend only on the concentration of particles of the solute, not their identity.For dilute solutions, Tband Tfare proportional to the molality of the solute in the solution.The vaues of Kb and Kf do depend on the properties of the solvent. For liquids, is almost constant . [Troutans Rule , this constant for most of the Unassociated liquids (not having any strong bonding like Hydrogen bonding in the liquid state) is equal to 90J/mol. ] For solutes undergoing change of molecular state is solution (ionization or association), the observed T values differ from the calculate ones using the above relations. In such situations, the relationships are modified as Where i = Vant Hoff factor, greater than unity for ionization and smaller than unity for association of the solute molecules.Q.Depression of freezing point of which of the following solutions does represent the cryoscopic constant of water?

A system of greater disorder of molecules is more probable. The disorder of molecules is reflected by the entropy of the system. A liquid vaporizes to form a more disordered gas. When a solulte is present , there is additional contribution to the entropy of the liquid due to increase randomness. As the entropy of solution is higher than that of pure liquid, there is weaker tendency to form the gas.Thus , a solute (non volatil e) lowers the vapour pressure of a liquid, and hence a higher booing point of the solution Similarly, the greater randomness of the solution opposes the tendency to freeze. In consequence, a lower the temperature must be reached for achieving the equilibrium between the solid (frozen solvent) and the solution . Elevation of B.Pt. Tband depression of F.Pt. Tfof a solution are the colligative properties which depend only on the concentration of particles of the solute, not their identity.For dilute solutions, Tband Tfare proportional to the molality of the solute in the solution.The vaues of Kb and Kf do depend on the properties of the solvent. For liquids, is almost constant . [Troutans Rule , this constant for most of the Unassociated liquids (not having any strong bonding like Hydrogen bonding in the liquid state) is equal to 90J/mol. ] For solutes undergoing change of molecular state is solution (ionization or association), the observed T values differ from the calculate ones using the above relations. In such situations, the relationships are modified as Where i = Vant Hoff factor, greater than unity for ionization and smaller than unity for association of the solute molecules.Q.A liquid possessing which of the following characteristics will be most suitable for determining the molecular mass of a compound by cryoscopic measurements?

A system of greater disorder of molecules is more probable. The disorder of molecules is reflected by the entropy of the system. A liquid vaporizes to form a more disordered gas. When a solulte is present , there is additional contribution to the entropy of the liquid due to increase randomness. As the entropy of solution is higher than that of pure liquid, there is weaker tendency to form the gas.Thus , a solute (non volatil e) lowers the vapour pressure of a liquid, and hence a higher booing point of the solution Similarly, the greater randomness of the solution opposes the tendency to freeze. In consequence, a lower the temperature must be reached for achieving the equilibrium between the solid (frozen solvent) and the solution . Elevation of B.Pt. Tband depression of F.Pt. Tfof a solution are the colligative properties which depend only on the concentration of particles of the solute, not their identity.For dilute solutions, Tband Tfare proportional to the molality of the solute in the solution.The vaues of Kb and Kf do depend on the properties of the solvent. For liquids, is almost constant . [Troutans Rule , this constant for most of the Unassociated liquids (not having any strong bonding like Hydrogen bonding in the liquid state) is equal to 90J/mol. ] For solutes undergoing change of molecular state is solution (ionization or association), the observed T values differ from the calculate ones using the above relations. In such situations, the relationships are modified as Where i = Vant Hoff factor, greater than unity for ionization and smaller than unity for association of the solute molecules.Q.A mixture of two immiscible liquids at a constant pressure of 1 atm boils at a temperature

Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer?
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Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer?.
Solutions for Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer? in English & in Hindi are available as part of our courses for JEE. Download more important topics, notes, lectures and mock test series for JEE Exam by signing up for free.
Here you can find the meaning of Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer?, a detailed solution for Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer? has been provided alongside types of Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Properties, whose values depend only on the concentration of solute particles in solution and not on the identity of the solute are called colligative properties. There may be change in number of moles of solute due to ionisation or association hence these properties are also affected. Number of moles of the product is related to degree of ionisation or association by vant Hoff factor ‘i’ given by i = [ 1 + (n – 1) α] for dissociationwhere n is the number of products (ions or molecules) obtained per mole of the reactant & i = for association.Where n is number of reactant particles associated to give 1 mole product.A dilute solution contains ‘t’ moles of solute X in 1 Kg of solvent with molal elevation constant Kb. The solute dimerises in the solution according to the following equation. The degree of association is α.Q.The colligative properties observed will be a)b)c)d)Correct answer is option 'A'. Can you explain this answer? tests, examples and also practice JEE tests.
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