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Which of the following will decrease with dilution at a given temperature?
  • a)
    pH of 10-3M acetic acid solution
  • b)
    pH of 10-3M aniline solution
  • c)
    degree of dissociation of 10-3M acetic acid
  • d)
    degree of dissociation of 10–3M aniline solution
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Which of the following will decrease with dilution at a given temperat...
Degree of dissocation of WA and WB will increase.
    [H+] in WA and [OH] in WB will decrease so pH of WA and pOH of WB will increase.
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Most Upvoted Answer
Which of the following will decrease with dilution at a given temperat...
-3M aniline solution

Dilution refers to the process of adding more solvent to a solution, which results in a decrease in the concentration of the solute.

a) The pH of 10-3M acetic acid solution will remain relatively constant with dilution because acetic acid is a weak acid and its pH is primarily determined by its dissociation constant.

b) The pH of 10-3M aniline solution will decrease with dilution. Aniline is a weak base, and as the concentration of aniline decreases with dilution, the pH of the solution will decrease.

c) The degree of dissociation of 10-3M acetic acid will remain relatively constant with dilution because it is determined by the dissociation constant and not affected by the concentration.

d) The degree of dissociation of 10-3M aniline will increase with dilution. As the concentration of aniline decreases, the equilibrium of the dissociation reaction will shift towards more dissociation, resulting in a higher degree of dissociation.
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A system of greater disorder of molecules is more probable. The disorder of molecules is reflected by the entropy of the system. A liquid vaporizes to form a more disordered gas. When a solulte is present , there is additional contribution to the entropy of the liquid due to increase randomness. As the entropy of solution is higher than that of pure liquid, there is weaker tendency to form the gas.Thus , a solute (non volatil e) lowers the vapour pressure of a liquid, and hence a higher booing point of the solution Similarly, the greater randomness of the solution opposes the tendency to freeze. In consequence, a lower the temperature must be reached for achieving the equilibrium between the solid (frozen solvent) and the solution . Elevation of B.Pt. Tband depression of F.Pt. Tfof a solution are the colligative properties which depend only on the concentration of particles of the solute, not their identity.For dilute solutions, Tband Tfare proportional to the molality of the solute in the solution.The vaues of Kb and Kf do depend on the properties of the solvent. For liquids, is almost constant . [Troutans Rule , this constant for most of the Unassociated liquids (not having any strong bonding like Hydrogen bonding in the liquid state) is equal to 90J/mol. ] For solutes undergoing change of molecular state is solution (ionization or association), the observed T values differ from the calculate ones using the above relations. In such situations, the relationships are modified as Where i = Vant Hoff factor, greater than unity for ionization and smaller than unity for association of the solute molecules.Q.Depression of freezing point of which of the following solutions does represent the cryoscopic constant of water?

Which of the following will decrease with dilution at a given temperature?a)pH of 10-3M acetic acid solutionb)pH of 10-3M aniline solutionc)degree of dissociation of 10-3M acetic acidd)degree of dissociation of 10–3M aniline solutionCorrect answer is option 'B'. Can you explain this answer?
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Which of the following will decrease with dilution at a given temperature?a)pH of 10-3M acetic acid solutionb)pH of 10-3M aniline solutionc)degree of dissociation of 10-3M acetic acidd)degree of dissociation of 10–3M aniline solutionCorrect answer is option 'B'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Which of the following will decrease with dilution at a given temperature?a)pH of 10-3M acetic acid solutionb)pH of 10-3M aniline solutionc)degree of dissociation of 10-3M acetic acidd)degree of dissociation of 10–3M aniline solutionCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following will decrease with dilution at a given temperature?a)pH of 10-3M acetic acid solutionb)pH of 10-3M aniline solutionc)degree of dissociation of 10-3M acetic acidd)degree of dissociation of 10–3M aniline solutionCorrect answer is option 'B'. Can you explain this answer?.
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