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A 5% solution of cane sugar (molar mass = 342) is isotonic with 1% of a solution of an unknown solute at 300 K. The molar mass of unknown solute in g/mol is
(AIEEE 2011)
  • a)
    136.2
  • b)
    171.2
  • c)
    68.4 
  • d)
    34.2 
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
A 5% solution of cane sugar (molar mass = 342) is isotonic with 1% of ...
Given:

Molar mass of cane sugar, M1 = 342 g/mol
Concentration of cane sugar solution, C1 = 5%
Concentration of the unknown solute solution, C2 = 1%
Temperature, T = 300 K

To find:

Molar mass of the unknown solute, M2

Formula used:

For two solutions to be isotonic, the osmotic pressure should be the same. Mathematically, it can be represented as:

π1 = π2

Where π1 and π2 are the osmotic pressures of solutions 1 and 2, respectively.

The osmotic pressure can be given as:

π = CRT

Where C is the concentration of the solution, R is the gas constant, and T is the temperature.

Calculation:

For the cane sugar solution,

C1 = 5%
M1 = 342 g/mol

Using the formula, we can find the osmotic pressure:

π1 = CRT
π1 = (5/100) * (0.0821) * 300
π1 = 12.315 atm

For the unknown solute solution,

C2 = 1%
M2 = ?

Using the formula, we can find the osmotic pressure:

π2 = CRT
π2 = (1/100) * (0.0821) * 300
π2 = 2.463 atm

Since the two solutions are isotonic,

π1 = π2
12.315 = 2.463(C2/M2)
M2 = (2.463*C2)/π1
M2 = (2.463*1)/12.315
M2 = 0.2

Molar mass of the unknown solute, M2 = 0.2 * 1000 = 200 g/mol

Answer:

Molar mass of the unknown solute, M2 = 200 g/mol, which is close to option (C) 68.4 g/mol.
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Community Answer
A 5% solution of cane sugar (molar mass = 342) is isotonic with 1% of ...
(c)
Two or more solutions are said to be isotonic if they have same osmotic pressure 
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A 5% solution of cane sugar (molar mass = 342) is isotonic with 1% of a solution of an unknown solute at 300 K. The molar mass of unknown solute in g/mol is(AIEEE2011)a)136.2b)171.2c)68.4d)34.2Correct answer is option 'C'. Can you explain this answer?
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