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The frequency for pure rotational spectrum in cm-1 for pure rotational in the spectrum of NO molecule due to change in the quantum no from J=1 to J= 2?
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Calculation of Frequency for Pure Rotational Spectrum of NO Molecule
The frequency for the pure rotational spectrum of a molecule can be calculated using the formula:
\[ \Delta E = B \times (J+1) - B \times J \]
where:
- \( \Delta E \) is the energy difference between two adjacent rotational levels
- B is the rotational constant of the molecule
- J is the quantum number representing the rotational level

Given Data:
- Change in quantum number, \( \Delta J = 2 - 1 = 1 \)

Calculation:
- Since \( \Delta E = B \times (J+1) - B \times J \), substituting \( \Delta J = 1 \) into the formula gives:
\[ \Delta E = B \times (1+1) - B \times 1 = B \]
- The frequency of the rotational transition can be calculated using the relation:
\[ \Delta E = h \times \nu \]
where:
- h is the Planck's constant
- \( \nu \) is the frequency
- Equating the two equations gives:
\[ B = h \times \nu \]
\[ \nu = \frac{B}{h} \]
- Finally, substituting the rotational constant for NO molecule and Planck's constant into the formula gives the frequency in cm\(^{-1}\).
Therefore, the frequency for the pure rotational spectrum in cm\(^{-1}\) due to the change in the quantum number from J=1 to J=2 for the NO molecule can be calculated using the above steps.
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The frequency for pure rotational spectrum in cm-1 for pure rotational in the spectrum of NO molecule due to change in the quantum no from J=1 to J= 2?
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