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A heat reservoir at 900 K is brought into contact with the ambient at 300 K for a short time. During this period 9000 kJ of heat is lost by the heat reservoir. The total loss in availability due to this process is
  • a)
    18000 kJ
  • b)
    9000 kJ
  • c)
    6000 kJ
  • d)
    None of these
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
A heat reservoir at 900 K is brought into contact with the ambient at ...
Entropy change for hot reservoir

Energy gain in cold reservoir

Loss in availability = T0 [ ΔSc + ΔSh ]
⇒ 300(30 – 10)
= 300(20)
= 6000 kJ
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Community Answer
A heat reservoir at 900 K is brought into contact with the ambient at ...
Loss in Availability Due to Heat Transfer

When a heat reservoir at a high temperature T1 is brought into contact with a heat sink at a lower temperature T2, heat will flow from the reservoir to the sink. The amount of heat transferred is given by:

Q = mC(T1 - T2)

where Q is the heat transferred, m is the mass of the substance, C is the specific heat capacity, and T1 and T2 are the temperatures of the reservoir and sink, respectively.

However, not all of the heat transferred is useful. Some of it is lost in the form of entropy. The amount of heat that can be converted to work is given by the change in availability:

A = Q - TS

where S is the entropy change and T is the temperature at which the transfer occurs. The change in availability is a measure of the useful work that can be obtained from the heat transfer.

Calculation of Loss in Availability

Given:

T1 = 900 K

T2 = 300 K

Q = 9000 kJ

We can calculate the change in entropy using the formula:

ΔS = Q/T

where Q is the heat transferred and T is the temperature at which the transfer occurs. Substituting the values, we get:

ΔS = 9000 kJ / 900 K = 10 kJ/K

The loss in availability is then given by:

A = Q - TS

A = 9000 kJ - 300 K * 10 kJ/K

A = 6000 kJ

Therefore, the total loss in availability due to the heat transfer is 6000 kJ.
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