Complete combustion of 0.858 g of compound X gives 2.63 g of CO and 1....
Given:
Mass of X = 0.858 g
Mass of CO produced = 2.63 g
Mass of HO produced = 1.28 g
To determine:
The lowest molecular mass X can have
Solution:
1. Find the moles of CO and HO produced using their respective molar masses:
Molar mass of CO = 12.01 + 15.99 = 28 g/mol
Moles of CO = 2.63 g / 28 g/mol = 0.094 mol
Molar mass of HO = 1.01 + 15.99 = 18.01 g/mol
Moles of HO = 1.28 g / 18.01 g/mol = 0.071 mol
2. Determine the limiting reactant:
The balanced chemical equation for the combustion of X is:
CₓHᵧ + (x + y/4)O₂ → xCO₂ + (y/2)H₂O
From the equation, we can see that 1 mole of X produces x moles of CO₂ and y/2 moles of H₂O. Therefore, the theoretical yield of CO and HO can be calculated as:
Theoretical yield of CO = x × moles of X
Theoretical yield of HO = (y/2) × moles of X
Using the masses of CO and HO produced, we can calculate the actual yield of each product:
Actual yield of CO = 2.63 g
Actual yield of HO = 1.28 g
Using the molar masses of CO and HO, we can calculate the number of moles produced:
Moles of CO produced = 0.094 mol
Moles of HO produced = 0.071 mol
To determine the limiting reactant, we need to compare the moles of CO and HO produced to their theoretical yields:
Theoretical yield of CO = x × moles of X
= x/2 × moles of X (since 1 mole of X produces x/2 moles of CO)
Theoretical yield of HO = (y/2) × moles of X
Comparing the moles of CO and HO produced to their theoretical yields:
Moles of CO produced = 0.094 mol
Theoretical yield of CO = x/2 × moles of X
Moles of HO produced = 0.071 mol
Theoretical yield of HO = (y/2) × moles of X
We need to find which value of x and y will give the lowest molecular mass of X.
3. Determine the molecular formula of X:
To determine the molecular formula of X, we need to find the values of x and y that satisfy the following conditions:
1. The moles of CO produced must be equal to the theoretical yield of CO:
0.094 mol = x/2 × moles of X
2. The moles of HO produced must be equal to the theoretical yield of HO:
0.071 mol = (y/2) × moles of X
To find the lowest molecular mass of X, we need to try different values of x and y. We can start with the smallest whole number values and increase until we find a combination that satisfies both conditions.
Let's try x = 2 and y = 2:
0.094 mol = 2/2 ×
Complete combustion of 0.858 g of compound X gives 2.63 g of CO and 1....
Given:
- Mass of compound X = 0.858 g
- Mass of CO produced = 2.63 g
- Mass of HO produced = 1.28 g
We need to find the lowest molecular mass X can have.
Approach:
1. Write the balanced chemical equation for the combustion of compound X.
2. Calculate the number of moles of CO and HO produced.
3. Calculate the number of moles of C and H in compound X.
4. Use the molecular formula of X to calculate its molecular mass.
5. Find the lowest molecular mass X can have.
Solution:
1. Balanced chemical equation for the combustion of compound X:
CₓHᵧOᵨ + (x + y/4 - r/2)O₂ → xCO₂ + (y/2)H₂O
From the balanced equation, we can see that for every x moles of compound X, we get x moles of CO₂ and y/2 moles of H₂O.
2. Calculation of the number of moles of CO and HO produced:
Number of moles of CO produced = Mass of CO produced / Molar mass of CO
Molar mass of CO = 12.01 + 15.99 = 28 g/mol
Number of moles of CO produced = 2.63 g / 28 g/mol = 0.094 moles
Number of moles of HO produced = Mass of HO produced / Molar mass of HO
Molar mass of HO = 1.01 + 15.99 = 18.01 g/mol
Number of moles of HO produced = 1.28 g / 18.01 g/mol = 0.071 moles
3. Calculation of the number of moles of C and H in compound X:
From the balanced equation, we can see that for every x moles of compound X, we get x moles of CO₂.
Number of moles of CO2 produced = Number of moles of CO produced = 0.094 moles
Since one mole of CO₂ contains one mole of C, we can say that the number of moles of C in compound X is also 0.094 moles.
From the balanced equation, we can see that for every x moles of compound X, we get y/2 moles of H₂O.
Number of moles of H₂O produced = Number of moles of HO produced / 0.5
Number of moles of H₂O produced = 0.071 moles / 0.5 = 0.142 moles
Since one mole of H₂O contains two moles of H, we can say that the number of moles of H in compound X is 0.284 moles.
4. Use the molecular formula of X to calculate its molecular mass:
Let the molecular formula of compound X be CₐHᵦOᵩ
The molar mass of X can be calculated as follows:
Molar mass of X = (a x 12.01) + (b x 1.01) + (o x 15.99)
5. Find the lowest molecular mass X can have:
We know that X contains 0.094 moles of C and 0.284 moles of H.
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