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for a reaction 2A+B gives product , doubling the initial concentration of both reactants increases the rate by a factor of 8, and doubling the concentration of B alone doubles the rate . the rate law for the reaction is
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for a reaction 2A+B gives product , doubling the initial concentration...
Rate Law for Reaction 2A B Gives Product


Introduction


The rate law for a chemical reaction gives us information about the rate of the reaction with respect to the concentrations of the reactants. In this case, we are given the reaction 2A B gives product and we need to determine the rate law for this reaction.

Experimental Data


We are given the following experimental data:

- Doubling the initial concentration of both reactants increases the rate by a factor of 8
- Doubling the concentration of B alone doubles the rate

Determining the Rate Law


We can determine the rate law for the reaction by using the experimental data to find the orders of reaction with respect to each reactant.

From the first piece of experimental data, we can see that the rate is proportional to the concentration of both A and B raised to some power. Let's call the order of reaction with respect to A "x" and the order of reaction with respect to B "y". Then, we can write:

rate = k[A]^x[B]^y

When we double the concentration of both A and B, the rate increases by a factor of 8. This means that:

(2[A])^x(2[B])^y = 8[A]^x[B]^y

Simplifying this expression, we get:

2^x * 2^y = 8

2^(x+y) = 8

x + y = 3

From the second piece of experimental data, we can see that doubling the concentration of B alone doubles the rate. This means that:

(2[A])^x(2[B])^y = 2[A]^x[2B]^y

Simplifying this expression, we get:

2^y = 2

y = 1

Now that we know the order of reaction with respect to B, we can use the first piece of experimental data to find the order of reaction with respect to A. We know that:

x + y = 3

y = 1

So:

x = 2

Therefore, the rate law for the reaction 2A B gives product is:

rate = k[A]^2[B]

Conclusion


In conclusion, the rate law for the reaction 2A B gives product is rate = k[A]^2[B]. We determined this rate law by using the experimental data given to us and finding the orders of reaction with respect to each reactant.
Community Answer
for a reaction 2A+B gives product , doubling the initial concentration...
2A+B->C
R1= k[A]^x[B]^y
doubling both concentration of reactants,
R2= k[2A]^x[2B]^y
R2=8R1...(1)
R3= k[A]^x[2B]^y, here deduce that Order of is 1.
R3=2R1....(2)
R2/R3=8/2=([2A]/[A])^x
4=2^x
x=2
so, the rate law will be R1= k[A]^2[B]^1
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Read the passage given below and answer the following questions:The rate of a reaction, which may also be called its velocity or speed, can be defined with relation to the concentration of any of the reacting substances, or to that of any product of the reaction. If the species chosen is a reactant which has a concentration c at time t the rate is - dc/dt, while the rate with reference to a product having a concentration x at time t is dx/dt. Any concentration units may be used for expressing the rate; thus, if moles per liter are employed for concentration and seconds for the time, the units for the rate are moles litre–1sec–1. For gas reactions pressure units are sometimes used in place of concentrations, so that legitimate units for the rate would be (mm. Hg) sec–1 and atm. sec–1 The order of a reaction concerns the dependence of the rate upon the concentrations of reacting substances; thus, if the rate is found experimentally to be proportional to the ath power of the concentration of one of the reactants A, to the both power of the concentration of a second reactant B, and so forth, via., rate = k CAα CAβ the over-all order of the reaction is simply n = α + β + ----- (2) Such a reaction is said to be of the αth order with respect to the substance A, the βth order with respect to B.In the following questions, a statement of Assertion followed by a statement of Reason is given. Choose the correct answer out of the following choices on the basis of the above passage.Assertion: For a reaction: P + 2Q → Products, Rate = k [P]1/2[Q]1 so the order of reaction is 1.5Reason: Order of reaction is the sum of stoichiometric coefficients of the reactants.

for a reaction 2A+B gives product , doubling the initial concentration of both reactants increases the rate by a factor of 8, and doubling the concentration of B alone doubles the rate . the rate law for the reaction is
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