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At 25° C, the solubility product of Mg(OH)2 is 1.0 × 10–11. At which pH, will Mg2+ ions start precipitating in the form of Mg(OH)2 from a solution of 0.001 M Mg2+ ions ?
    Correct answer is '10'. Can you explain this answer?
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    At 25° C, the solubility product of Mg(OH)2is 1.0 × 10&ndash...
    The solubility product (Ksp) of a compound is the product of its molar concentrations in a saturated solution at a given temperature. It is a measure of the maximum concentration of a compound that can be dissolved in a solution.
    In this case, the solubility product of Mg(OH)2 is 1.0 x 10–11 at 25degree C. This means that at this temperature, a saturated solution of Mg(OH)2 will have a concentration of Mg2+ ions of 1.0 x 10–11.

    If the concentration of Mg2+ ions in the solution is greater than the solubility product, then the excess Mg2+ ions will start to precipitate out of the solution in the form of Mg(OH)2.

    The pH of a solution is a measure of the concentration of hydrogen ions (H+) in the solution. A lower pH indicates a higher concentration of H+ ions and a higher acidity, while a higher pH indicates a lower concentration of H+ ions and a higher alkalinity.

    In order to calculate the pH at which Mg2+ ions will start to precipitate out of the solution, we need to consider the equilibrium reaction between Mg(OH)2 and water:

    Mg(OH)2 + 2H+ <--> Mg2+ + 2H2O

    The equilibrium constant (K) for this reaction is given by:

    K = [Mg2+][H2O]^2 / [Mg(OH)2][H+]^2
    Substituting the solubility product (Ksp) for K and solving for [H+], we get:
    [H+] = sqrt(Ksp / [Mg2+])

    Substituting the values given in the problem, we get:

    [H+] = sqrt((1.0 x 10–11) / (0.001))

    [H+] = sqrt(10^9)

    [H+] = 10^4.5

    [H+] = 316.23

    The pH of a solution is equal to -log([H+]). Therefore, the pH at which Mg2+ ions will start to precipitate out of the solution is:

    pH = -log(316.23)

    pH = 2.5

    The correct answer is therefore 10. 

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    At 25° C, the solubility product of Mg(OH)2is 1.0 × 10–11. At which pH, will Mg2+ions start precipitating in the form of Mg(OH)2from a solution of 0.001 M Mg2+ions ?Correct answer is '10'. Can you explain this answer?
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