Direction: In the following questions a statement of Assertion (A) fo...
Canonical structures always have more energy than resonance hybrid. Resonance hybrids are always more stable than any of the canonical structures. The delocalization of electrons lowers the orbitals energy and gives stability.
View all questions of this test
Direction: In the following questions a statement of Assertion (A) fo...
Assertion (A): Energy of resonance hybrid is equal to the average of energies of all canonical forms.
Reason (R): Resonance hybrid cannot be presented by a single structure.
The correct option out of the choices given below the question is D, which means Assertion (A) is not correct but Reason (R) is correct.
Explanation:
Resonance is a phenomenon observed in molecules where the electrons are delocalized and can be represented by multiple resonance structures or canonical forms. The actual electronic structure of the molecule is a hybrid of these resonance structures, known as the resonance hybrid.
Assertion (A): Energy of resonance hybrid is equal to the average of energies of all canonical forms.
This statement is incorrect. The energy of the resonance hybrid is not equal to the average of energies of all canonical forms. In a resonance hybrid, the energy is actually lower than the energy of any of the individual canonical forms. This is because the delocalization of electrons in the resonance hybrid leads to greater stability. The resonance hybrid represents a more stable state of the molecule compared to any single canonical form.
Reason (R): Resonance hybrid cannot be presented by a single structure.
This statement is correct. Resonance hybrid cannot be represented by a single structure because the actual electronic structure of the molecule is a combination or hybrid of all the resonance structures. Each resonance structure contributes to the overall stability and properties of the molecule, and therefore, it is not possible to represent the molecule by a single structure.
The resonance hybrid is a representation of the actual electronic structure of the molecule, which takes into account the delocalization of electrons. It is important to note that the resonance hybrid is not a real physical structure but a theoretical concept used to describe the electronic structure of molecules with delocalized electrons.
In conclusion, the energy of the resonance hybrid is lower than the energy of any single canonical form, and the resonance hybrid cannot be represented by a single structure.
To make sure you are not studying endlessly, EduRev has designed Class 11 study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in Class 11.