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Read the passage given below and answer the following questions:
The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.
The following questions are multiple choice questions. Choose the most appropriate answer:
Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.
  • a)
    [Co(H2O)6]2+ is transformed into [CoCl6]4−
  • b)
    [Co(H2O)6]2+ is transformed into [CoCl4]2−
  • c)
    tetrahedral complexes have larger crystal field splitting than octahedral complex.
  • d)
    None of the above
Correct answer is option 'B'. Can you explain this answer?
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Read the passage given below and answer the following questions:The c...
[Co(H2O)6]2+ is transformed into [CoCl4]2−.
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Read the passage given below and answer the following questions:The c...

Explanation:

Reason for color change:
- The aqueous pink solution of cobalt(II) chloride contains [Co(H2O)6]2+ ions.
- Upon addition of excess HCl, the [Co(H2O)6]2+ ions are transformed into [CoCl4]2- ions.
- This transformation leads to a change in the color of the solution from pink to deep blue.

Explanation of the transformation:
- When excess HCl is added, Cl- ions from HCl replace the water ligands in the complex.
- The resulting complex [CoCl4]2- has a tetrahedral geometry, with chlorine ions occupying the coordination sites around the cobalt ion.
- The tetrahedral complex [CoCl4]2- has a larger crystal field splitting compared to the octahedral complex [Co(H2O)6]2+.
- This difference in crystal field splitting causes the color change from pink to deep blue.

Conclusion:
- The change in color of the cobalt(II) chloride solution from pink to deep blue upon addition of excess HCl is due to the transformation of [Co(H2O)6]2+ ions into [CoCl4]2- ions, which have a larger crystal field splitting in the tetrahedral complex.
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Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer?
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Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer?.
Solutions for Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer? in English & in Hindi are available as part of our courses for Class 12. Download more important topics, notes, lectures and mock test series for Class 12 Exam by signing up for free.
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An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer?, a detailed solution for Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer? has been provided alongside types of Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Read the passage given below and answer the following questions:The crystal field theory (CFT) is an electrostatic model which considers the metal-ligand bond to be ionic arising purely from electrostatic interactions between the metal ion and the ligand. Ligands are treated as point charges in case of anions or dipoles in case of neutral molecules. The five d orbitals in an isolated gaseous metal atom/ion have same energy, i.e., they are degenerate. This degeneracy is maintained if a spherically symmetrical field of negative charges surrounds the metal atom/ ion. However, when this negative field is due to ligands (either anions or the negative ends of dipolar molecules like NH3 and H2O) in a complex, it becomes asymmetrical and the degeneracy of the d orbitals is lifted. It results in splitting of the d orbitals.The following questions are multiple choice questions. Choose the most appropriate answer:Q. An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCl. This is because _____________.a)[Co(H2O)6]2+ is transformed into [CoCl6]4−b)[Co(H2O)6]2+ is transformed into [CoCl4]2−c)tetrahedral complexes have larger crystal field splitting than octahedral complex.d)None of the aboveCorrect answer is option 'B'. Can you explain this answer? tests, examples and also practice Class 12 tests.
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