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Entropy is a measure of degree of randomness. Entropy is directly proportional to temperature. Every system tries to acquire maximum state of randomness or disorder. Entropy is a measure of unavailable energy. Unavailable energy = Entropy × Temperature The ratio of Entropy of Vaporization and boiling point of a substance remains almost constant. Answer the given below questions (i) to (iv).
Q. Which of the following has S = +ve?
  • a)
    H2 (g) + Cl2 (g) → 2HCl (g)
  • b)
    Boiling of egg
  • c)
    Crystallization of Sugar
  • d)
    Formation of Complex Compound
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Entropy is a measure of degree of randomness. Entropy is directly pro...
Boiling of egg leads to denaturation of proteins which has random coil structure. Hence, ΔS = +ve.
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Entropy is a measure of degree of randomness. Entropy is directly pro...
Answer:

To determine which process has a change in entropy (S) equal to zero, we need to understand the concept of entropy and its relationship with randomness and disorder.

1. Entropy:
- Entropy is a measure of the degree of randomness or disorder in a system.
- It quantifies the number of possible arrangements or microstates that a system can have.
- The higher the entropy, the greater the degree of randomness or disorder in the system.

2. Relationship between Entropy and Temperature:
- Entropy is directly proportional to temperature.
- As the temperature increases, the entropy also increases.
- This is because at higher temperatures, the particles in the system have more energy and are more likely to be in a greater number of possible arrangements, increasing the randomness or disorder.

3. Unavailable Energy and Entropy:
- Unavailable energy is the energy that cannot be used to do work.
- It is directly related to entropy and temperature.
- The equation for unavailable energy is: Unavailable energy = Entropy × Temperature.

4. Entropy of Vaporization and Boiling Point:
- The ratio of the entropy of vaporization to the boiling point of a substance remains almost constant.
- This means that the change in entropy during vaporization is relatively constant compared to the boiling point of the substance.

Analysis of the Options:

(i) H2 (g) + Cl2 (g) → 2HCl (g)
- This is a chemical reaction where hydrogen gas and chlorine gas combine to form hydrogen chloride gas.
- The reaction involves a change in the arrangement and bonding of the particles, leading to an increase in randomness or disorder.
- Therefore, the entropy change is not zero.

(ii) Boiling of an egg
- Boiling an egg involves the conversion of liquid egg white and yolk into a solid state.
- The change in state from liquid to solid does not involve a significant change in the arrangement or randomness of the particles.
- Therefore, the entropy change is close to zero.

(iii) Crystallization of Sugar
- Crystallization of sugar involves the formation of regular, repeating patterns of sugar molecules.
- This leads to a decrease in randomness or disorder, resulting in a decrease in entropy.
- Therefore, the entropy change is not zero.

(iv) Formation of Complex Compound
- The formation of a complex compound can involve various reactions and rearrangements of particles.
- This usually leads to an increase in randomness or disorder, resulting in an increase in entropy.
- Therefore, the entropy change is not zero.

Conclusion:
- Among the given options, the boiling of an egg has the entropy change closest to zero.
- This is because the change in state from liquid to solid during the boiling process does not involve a significant change in the arrangement or randomness of the particles, leading to a minimal change in entropy.
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Entropy is a measure of degree of randomness. Entropy is directly proportional to temperature. Every system tries to acquire maximum state of randomness or disorder. Entropy is a measure of unavailable energy. Unavailable energy = Entropy × Temperature The ratio of Entropy of Vaporization and boiling point of a substance remains almost constant. Answer the given below questions (i) to (iv).Q. Which of the following has S = +ve?a)H2 (g) + Cl2 (g) → 2HCl (g)b)Boiling of eggc)Crystallization of Sugard)Formation of Complex CompoundCorrect answer is option 'B'. Can you explain this answer?
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Entropy is a measure of degree of randomness. Entropy is directly proportional to temperature. Every system tries to acquire maximum state of randomness or disorder. Entropy is a measure of unavailable energy. Unavailable energy = Entropy × Temperature The ratio of Entropy of Vaporization and boiling point of a substance remains almost constant. Answer the given below questions (i) to (iv).Q. Which of the following has S = +ve?a)H2 (g) + Cl2 (g) → 2HCl (g)b)Boiling of eggc)Crystallization of Sugard)Formation of Complex CompoundCorrect answer is option 'B'. Can you explain this answer? for Class 11 2024 is part of Class 11 preparation. The Question and answers have been prepared according to the Class 11 exam syllabus. Information about Entropy is a measure of degree of randomness. Entropy is directly proportional to temperature. Every system tries to acquire maximum state of randomness or disorder. Entropy is a measure of unavailable energy. Unavailable energy = Entropy × Temperature The ratio of Entropy of Vaporization and boiling point of a substance remains almost constant. Answer the given below questions (i) to (iv).Q. Which of the following has S = +ve?a)H2 (g) + Cl2 (g) → 2HCl (g)b)Boiling of eggc)Crystallization of Sugard)Formation of Complex CompoundCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for Class 11 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Entropy is a measure of degree of randomness. Entropy is directly proportional to temperature. Every system tries to acquire maximum state of randomness or disorder. Entropy is a measure of unavailable energy. Unavailable energy = Entropy × Temperature The ratio of Entropy of Vaporization and boiling point of a substance remains almost constant. Answer the given below questions (i) to (iv).Q. Which of the following has S = +ve?a)H2 (g) + Cl2 (g) → 2HCl (g)b)Boiling of eggc)Crystallization of Sugard)Formation of Complex CompoundCorrect answer is option 'B'. Can you explain this answer?.
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